Spin hyperpolarization in modern magnetic resonance

J Eills, D Budker, S Cavagnero, EY Chekmenev… - Chemical …, 2023 - ACS Publications
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …

Practical dissolution dynamic nuclear polarization

SJ Elliott, Q Stern, M Ceillier, T El Daraï… - Progress in Nuclear …, 2021 - Elsevier
This review article intends to provide insightful advice for dissolution-dynamic nuclear
polarization in the form of a practical handbook. The goal is to aid research groups to …

Single-Site Iridium Picolinamide Catalyst Immobilized onto Silica for the Hydrogenation of CO2 and the Dehydrogenation of Formic Acid

L Tensi, AV Yakimov, C Trotta, C Domestici… - Inorganic …, 2022 - ACS Publications
The development of an efficient heterogeneous catalyst for storing H2 into CO2 and
releasing it from the produced formic acid, when needed, is a crucial target for overcoming …

Porous functionalized polymers enable generating and transporting hyperpolarized mixtures of metabolites

T El Daraï, SF Cousin, Q Stern, M Ceillier… - Nature …, 2021 - nature.com
Hyperpolarization by dissolution dynamic nuclear polarization (dDNP) has enabled
promising applications in spectroscopy and imaging, but remains poorly widespread due to …

Speciation and structures in Pt surface sites stabilized by N-heterocyclic carbene ligands revealed by dynamic nuclear polarization enhanced indirectly detected …

Z Wang, LA Völker, TC Robinson… - Journal of the …, 2022 - ACS Publications
N-Heterocyclic carbenes (NHCs) are widely used ligands in transition metal catalysis.
Notably, they are increasingly encountered in heterogeneous systems. While a detailed …

Triplet dynamic nuclear polarization of guest molecules through induced fit in a flexible metal–organic framework

S Fujiwara, N Matsumoto, K Nishimura… - Angewandte Chemie …, 2022 - Wiley Online Library
Dynamic nuclear polarization utilizing photoexcited triplet electrons (triplet‐DNP) has great
potential for room‐temperature hyperpolarization of nuclear spins. However, the polarization …

Scaling analyses for hyperpolarization transfer across a spin-diffusion barrier and into bulk solid media

NA Prisco, AC Pinon, L Emsley… - Physical Chemistry …, 2021 - pubs.rsc.org
By analogy to heat and mass transfer film theory, a general approach is introduced for
determining hyperpolarization transfer rates between dilute electron spins and a …

Performance and reproducibility of 13C and 15N hyperpolarization using a cryogen-free DNP polarizer

A Ferrari, J Peters, M Anikeeva, A Pravdivtsev… - Scientific reports, 2022 - nature.com
The setup, operational procedures and performance of a cryogen-free device for producing
hyperpolarized contrast agents using dissolution dynamic nuclear polarization (dDNP) in a …

Monitoring crystallization processes in confined porous materials by dynamic nuclear polarization solid-state nuclear magnetic resonance

M Juramy, R Chèvre, P Cerreia Vioglio… - Journal of the …, 2021 - ACS Publications
Establishing mechanistic understanding of crystallization processes at the molecular level is
challenging, as it requires both the detection of transient solid phases and monitoring the …

[HTML][HTML] An automated system for fast transfer and injection of hyperpolarized solutions

M Ceillier, O Cala, T El Daraï, SF Cousin… - Journal of Magnetic …, 2021 - Elsevier
Dissolution dynamic nuclear polarization (dDNP) has become a hyperpolarization method of
choice for enhancing nuclear magnetic resonance (NMR) signals. Nuclear spins are …