The chaotropic effect as an assembly motif in chemistry
Following up on scattered reports on interactions of conventional chaotropic ions (for
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …
Boron hydrogen compounds: hydrogen storage and battery applications
H Hagemann - Molecules, 2021 - mdpi.com
About 25 years ago, Bogdanovic and Schwickardi (B. Bogdanovic, M. Schwickardi: J. Alloys
Compd. 1–9, 253 (1997) discovered the catalyzed release of hydrogen from NaAlH4. This …
Compd. 1–9, 253 (1997) discovered the catalyzed release of hydrogen from NaAlH4. This …
Water structure recovery in chaotropic anion recognition: high‐affinity binding of dodecaborate clusters to γ‐cyclodextrin
KI Assaf, MS Ural, F Pan, T Georgiev… - Angewandte Chemie …, 2015 - Wiley Online Library
Dodecaborate anions of the type B12X122− and B12X11Y2−(X= H, Cl, Br, I and Y= OH, SH,
NH3+, NR3+) form strong (Ka up to 106 L mol− 1, for B12Br122−) inclusion complexes with …
NH3+, NR3+) form strong (Ka up to 106 L mol− 1, for B12Br122−) inclusion complexes with …
Closo‐Borate Gel Polymer Electrolyte with Remarkable Electrochemical Stability and a Wide Operating Temperature Window
M Green, K Kaydanik, M Orozco, L Hanna… - Advanced …, 2022 - Wiley Online Library
A major challenge in the pursuit of higher‐energy‐density lithium batteries for carbon‐
neutral‐mobility is electrolyte compatibility with a lithium metal electrode. This study …
neutral‐mobility is electrolyte compatibility with a lithium metal electrode. This study …
Der chaotrope Effekt als Aufbaumotiv in der Chemie
Abstract Nach vereinzelten Berichten zu Wechselwirkungen klassischer chaotroper Ionen (z.
B. I−, SCN−, ClO4−) mit makrocyclischen Wirtmolekülen, Biomolekülen und hydrophoben …
B. I−, SCN−, ClO4−) mit makrocyclischen Wirtmolekülen, Biomolekülen und hydrophoben …
On the solubility and lipophilicity of metallacarborane pharmacophores
J Rak, B Dejlová, H Lampová, R Kaplánek… - Molecular …, 2013 - ACS Publications
Metallacarborane moieties have been identified as promising pharmacophores. The
pharmaceutical use of such compounds is, however, complicated by their low solubility and …
pharmaceutical use of such compounds is, however, complicated by their low solubility and …
Coordination and thermodynamic properties of aqueous protactinium (V) by first-principle calculations
Protactinium (Z= 91) is a very rare actinide with peculiar physico-chemical properties.
Indeed, although one may naively think that it behaves similarly to either thorium or uranium …
Indeed, although one may naively think that it behaves similarly to either thorium or uranium …
Redox Energetics of Hypercloso Boron Hydrides BnHn (n = 6–13) and B12X12 (X = F, Cl, OH, and CH3)
The reduction potentials (E° Red versus SHE) of hypercloso boron hydrides B n H n (n= 6–
13) and B12X12 (X= F, Cl, OH, and CH3) in water have been computed using the Conductor …
13) and B12X12 (X= F, Cl, OH, and CH3) in water have been computed using the Conductor …
Groups 1 and 2
RB Jordan - Principles of Inorganic Chemistry: Basics and …, 2024 - Springer
This chapter covers the nonradioactive elements of Group 1 (H to Cs), known as the alkali
metals, and Group 2 (Be to Ba), known as the alkaline earth metals. Many properties of …
metals, and Group 2 (Be to Ba), known as the alkaline earth metals. Many properties of …
[PDF][PDF] Closo-borate Electrolytes for Improved Performance and Safety in Next Generation Battery Systems
MM Green - 2023 - scholarworks.calstate.edu
Lithium-ion batteries (LIB) have become a ubiquitous part of modern life due to their high
gravimetric energy density compared to other battery technologies. With applications in …
gravimetric energy density compared to other battery technologies. With applications in …