Using nature's blueprint to expand catalysis with Earth-abundant metals

RM Bullock, JG Chen, L Gagliardi, PJ Chirik, OK Farha… - Science, 2020 - science.org
BACKGROUND Catalysis has had a transformative impact on society, playing a crucial role
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …

Synergic heterodinuclear catalysts for the ring-opening copolymerization (ROCOP) of epoxides, carbon dioxide, and anhydrides

WT Diment, W Lindeboom, F Fiorentini… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The development of sustainable plastic materials is an essential target of
chemistry in the 21st century. Key objectives toward this goal include utilizing sustainable …

Understanding catalytic synergy in dinuclear polymerization catalysts for sustainable polymers

F Fiorentini, WT Diment, AC Deacy, RWF Kerr… - Nature …, 2023 - nature.com
Understanding the chemistry underpinning intermetallic synergy and the discovery of
generally applicable structure-performances relationships are major challenges in catalysis …

Co(III)/Alkali-Metal(I) Heterodinuclear Catalysts for the Ring-Opening Copolymerization of CO2 and Propylene Oxide

AC Deacy, E Moreby, A Phanopoulos… - Journal of the …, 2020 - ACS Publications
The ring-opening copolymerization of carbon dioxide and propene oxide is a useful means
to valorize waste into commercially attractive poly (propylene carbonate)(PPC) polyols. The …

Electric fields in catalysis: From enzymes to molecular catalysts

NG Léonard, R Dhaoui, T Chantarojsiri, JY Yang - ACS catalysis, 2021 - ACS Publications
Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …

Adsorbed cobalt porphyrins act like metal surfaces in electrocatalysis

CJ Kaminsky, S Weng, J Wright, Y Surendranath - Nature Catalysis, 2022 - nature.com
Electrodes chemically modified with molecular active sites are potent catalysts for energy
conversion reactions. Such electrodes are typically presumed to operate by the same redox …

Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin

DJ Martin, JM Mayer - Journal of the American Chemical Society, 2021 - ACS Publications
Next-generation energy technologies require improved methods for rapid and efficient
chemical-to-electrical energy transformations. One new approach has been to include …

Enhancing a Molecular Electrocatalyst's Activity for CO2 Reduction by Simultaneously Modulating Three Substituent Effects

W Nie, DE Tarnopol, CCL McCrory - Journal of the American …, 2021 - ACS Publications
The electrocatalytic activity for CO2 reduction is greatly enhanced for Co complexes with
pyridyldiimine-based ligands through the stepwise integration of three synergistic …

Spontaneous electric fields play a key role in thermochemical catalysis at metal− liquid interfaces

TS Wesley, Y Román-Leshkov… - ACS Central …, 2021 - ACS Publications
Large oriented electric fields spontaneously arise at all solid–liquid interfaces via the
exchange of ions and/or electrons with the solution. Although intrinsic electric fields are …

Strategies for breaking molecular scaling relationships for the electrochemical CO 2 reduction reaction

W Nie, CCL McCrory - Dalton Transactions, 2022 - pubs.rsc.org
The electrocatalytic CO2 reduction reaction (CO2RR) is a promising strategy for converting
CO2 to fuels and value-added chemicals using renewable energy sources. Molecular …