Porphyrins and phthalocyanines as biomimetic tools for photocatalytic H 2 production and CO 2 reduction

E Nikoloudakis, I López-Duarte… - Chemical Society …, 2022 - pubs.rsc.org
The increasing energy demand and environmental issues caused by the over-exploitation of
fossil fuels render the need for renewable, clean, and environmentally benign energy …

Recent advances in dye-sensitized semiconductor systems for photocatalytic hydrogen production

X Zhang, T Peng, S Song - Journal of Materials Chemistry A, 2016 - pubs.rsc.org
Photocatalytic water splitting by solar light has received tremendous attention for the
production of clean and renewable hydrogen energy from water. Some challenges still …

Recent advances in photocatalytic oxidation of 5‐hydroxymethylfurfural

C Li, Y Na - ChemPhotoChem, 2021 - Wiley Online Library
Conversion of biomass‐derived platform compounds into value‐added chemicals will
reduced the current dependence on carbon resources from fossil reserves. In recent years …

Alternative route to bypass the bottle-neck of water oxidation: Two-electron oxidation of water catalyzed by earth-abundant metalloporphyrins

F Kuttassery, S Mathew, SN Remello, A Thomas… - Coordination Chemistry …, 2018 - Elsevier
Recent development on alternative route to bypass the bottle-neck of water oxidation, two-
electron oxidation of water catalyzed by earth-abundant metalloporphyrins to form hydrogen …

One Electron‐Initiated Two‐Electron Oxidation of Water by Aluminum Porphyrins with Earth's Most Abundant Metal

F Kuttassery, S Mathew, S Sagawa… - …, 2017 - Wiley Online Library
We report herein a new molecular catalyst for efficient water splitting, aluminum porphyrins
(tetra‐methylpyridiniumylporphyrinatealuminum: AlTMPyP), containing earth's most …

Molecular Characteristics of Water-Insoluble Tin-Porphyrins for Designing the One-Photon-Induced Two-Electron Oxidation of Water in Artificial Photosynthesis

A Thomas, Y Ohsaki, R Nakazato, F Kuttassery… - Molecules, 2023 - mdpi.com
Faced with the new stage of water oxidation by molecular catalysts (MCs) in artificial
photosynthesis to overcome the bottle neck issue, the “Photon-flux density problem of …

Influence of meso-substitution of the porphyrin ring on enhanced hydrogen evolution in a photochemical system

E Koposova, X Liu, A Pendin, B Thiele… - The Journal of …, 2016 - ACS Publications
This study establishes the relationships between the structure of a series of meso-
substituted tin (IV) porphyrins and their efficiency as photosensitizers for hydrogen …

Promotive Effect of Bicarbonate Ion on Two‐Electron Water Oxidation to Form H2O2 Catalyzed by Aluminum Porphyrins

F Kuttassery, A Sebastian, S Mathew… - …, 2019 - Wiley Online Library
Two‐electron water oxidation initiated by one‐electron oxidation of aluminum porphyrins
(AlTMPyP) is an alternative water oxidation to the conventional four‐electron pathway and …

Preparation of NIR absorbing axial substituted tin (iv) porphyrins and their photocytotoxic properties

B Babu, E Amuhaya, D Oluwole, E Prinsloo, J Mack… - …, 2019 - pubs.rsc.org
Sn (IV) porphyrins ([Sn (IV) TTP (3PyO) 2](5) and [Sn (IV) TPP (3PyO) 2](6)[
tetrathienylporphyrin (TTP), tetraphenylporphyrin (TPP), and pyridyloxy (PyO)]) were …

Highly efficient light-driven hydrogen evolution utilizing porphyrin-based nanoparticles

V Nikolaou, E Agapaki, E Nikoloudakis… - Chemical …, 2023 - pubs.rsc.org
We developed dye-sensitized photocatalytic systems (DSPs) by utilizing porphyrins as a
photosensitizer (PS) or as a photosensitizer–catalyst (PS/CAT) upon their chemisorption …