Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Heterogeneous catalysts for CO 2 hydrogenation to formic acid/formate: from nanoscale to single atom

R Sun, Y Liao, ST Bai, M Zheng, C Zhou… - Energy & …, 2021 - pubs.rsc.org
Propelled by the vision of carbon-neutral energy systems, heterogeneous hydrogenation of
CO2 to formic acid/formate, a liquid hydrogen carrier, has been intensively studied as a …

Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols

K Sordakis, C Tang, LK Vogt, H Junge… - Chemical …, 2018 - ACS Publications
Hydrogen gas is a storable form of chemical energy that could complement intermittent
renewable energy conversion. One of the main disadvantages of hydrogen gas arises from …

Heterogeneous catalysis for carbon dioxide mediated hydrogen storage technology based on formic acid

M Liu, Y Xu, Y Meng, L Wang, H Wang… - Advanced Energy …, 2022 - Wiley Online Library
In the context of global carbon dioxide increasing drastically, renewable energy is crucial
maintain the economic growth of the world. Hydrogen has attracted considerable attention …

Iron catalysis in reduction and hydrometalation reactions

D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …

Enabling storage and utilization of low-carbon electricity: power to formic acid

S Chatterjee, I Dutta, Y Lum, Z Lai… - Energy & Environmental …, 2021 - pubs.rsc.org
Formic acid has been proposed as a hydrogen energy carrier because of its many desirable
properties, such as low toxicity and flammability, and a high volumetric hydrogen storage …

Manganese complexes for (de) hydrogenation catalysis: a comparison to cobalt and iron catalysts

F Kallmeier, R Kempe - Angewandte Chemie International …, 2018 - Wiley Online Library
The sustainable use of the resources on our planet is essential. Noble metals are very rare
and are diversely used in key technologies, such as catalysis. Manganese is the third most …

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

WH Wang, Y Himeda, JT Muckerman… - Chemical …, 2015 - ACS Publications
Carbon dioxide is one of the end products of combustion, and is not a benign component of
the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented …

Selective catalytic synthesis using the combination of carbon dioxide and hydrogen: catalytic chess at the interface of energy and chemistry

J Klankermayer, S Wesselbaum… - Angewandte Chemie …, 2016 - Wiley Online Library
The present Review highlights the challenges and opportunities when using the
combination CO2/H2 as a C1 synthon in catalytic reactions and processes. The …

Formic acid as a hydrogen storage material–development of homogeneous catalysts for selective hydrogen release

D Mellmann, P Sponholz, H Junge… - Chemical Society Reviews, 2016 - pubs.rsc.org
Formic acid (FA, HCO2H) receives considerable attention as a hydrogen storage material. In
this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction …