The RbSr 2 Σ+ ground state investigated via spectroscopy of hot and ultracold molecules

A Ciamei, J Szczepkowski, A Bayerle… - Physical Chemistry …, 2018 - pubs.rsc.org
We report on spectroscopic studies of hot and ultracold RbSr molecules, and combine the
results in an analysis that allows us to fit a potential energy curve (PEC) for the X (1) 2Σ+ …

Electric dipole moments and chemical bonding of diatomic alkali–alkaline earth molecules

JV Pototschnig, AW Hauser, WE Ernst - Physical Chemistry Chemical …, 2016 - pubs.rsc.org
We investigate the properties of alkali–alkaline earth diatomic molecules in the lowest Σ+
states of the doublet and quartet multiplicity by ab initio calculations. In all sixteen cases …

Electronic spectroscopy and photoionization of LiMg

TD Persinger, J Han, MC Heaven - The Journal of Physical …, 2021 - ACS Publications
Dimers consisting of an alkali metal bound to an alkaline earth metal are of interest from the
perspectives of their bonding characteristics and their potential for being laser cooled to …

Diatomic molecules of alkali-metal and alkaline-earth-metal atoms: interaction potentials, dipole moments, and polarizabilities

H Ladjimi, M Tomza - Physical Review A, 2024 - APS
Ultracold diatomic molecules find application in quantum studies ranging from controlled
chemistry and precision measurement physics to quantum many-body simulation and …

Helium-droplet-assisted preparation of cold RbSr molecules

F Lackner, G Krois, T Buchsteiner, JV Pototschnig… - Physical review …, 2014 - APS
We present a combined experimental and theoretical study of the RbSr molecule. The
experimental approach is based on the formation of RbSr molecules on helium …

Proposal for the formation of ultracold deeply bound RbSr dipolar molecules by all-optical methods

A Devolder, E Luc-Koenig, O Atabek… - Physical Review A, 2018 - APS
Ultracold paramagnetic and polar diatomic molecules are among the promising systems for
quantum simulation of lattice-spin models. Unfortunately, their experimental observation is …

Vibronic transitions in the alkali-metal (Li, Na, K, Rb)–alkaline-earth-metal (Ca, Sr) series: A systematic analysis of de-excitation mechanisms based on the graphical …

JV Pototschnig, R Meyer, AW Hauser, WE Ernst - Physical Review A, 2017 - APS
Research on ultracold molecules has seen a growing interest recently in the context of high-
resolution spectroscopy and quantum computation. After forming weakly bound molecules …

Ab initio study of the RbSr electronic structure: Potential energy curves, transition dipole moments, and permanent electric dipole moments

JV Pototschnig, G Krois, F Lackner… - The Journal of Chemical …, 2014 - pubs.aip.org
Excited states and the ground state of the diatomic molecule RbSr were calculated by post
Hartree-Fock molecular orbital theory up to 22 000 cm− 1. We applied a multireference …

Theoretical electronic structure of the molecules SrX (X= Li, Na, K) toward laser cooling study

I Zeid, T Atallah, S Kontar, W Chmaisani… - Computational and …, 2018 - Elsevier
The potential energy curves of the low-lying electronic states of the SrX (X= Li, Na, K)
molecules have been investigated by using the ab initio CASSCF/(MRCI+ Q) calculation. For …

[HTML][HTML] Investigation of the RbCa molecule: Experiment and theory

JV Pototschnig, G Krois, F Lackner, WE Ernst - Journal of molecular …, 2015 - Elsevier
We present a thorough theoretical and experimental study of the electronic structure of
RbCa. The mixed alkali–alkaline earth molecule RbCa was formed on superfluid helium …