Metal complex catalysis in the synthesis of spirocarbocycles

VA D'yakonov, OA Trapeznikova, A de Meijere… - Chemical …, 2014 - ACS Publications
Spirans contain at least two rings, which share one carbon atom called the spirocarbon
atom. 1 Synthetic and natural spirocarbocycles attract the attention of organic chemists due …

Metathesis in the synthesis of aromatic compounds

WAL van Otterlo, CB De Koning - Chemical reviews, 2009 - ACS Publications
The importance of aromatic structures in organic chemistry can never be underestimated.
Nature uses compounds containing aromatic or heteroaromatic nuclei extensively as the …

A general model for selectivity in olefin cross metathesis

AK Chatterjee, TL Choi, DP Sanders… - Journal of the American …, 2003 - ACS Publications
In recent years, olefin cross metathesis (CM) has emerged as a powerful and convenient
synthetic technique in organic chemistry; however, as a general synthetic method, CM has …

Synthesis of functionalized vinyl boronates via ruthenium-catalyzed olefin cross-metathesis and subsequent conversion to vinyl halides

C Morrill, RH Grubbs - The Journal of Organic Chemistry, 2003 - ACS Publications
Functionalized vinyl pinacol boronates suitable for Suzuki cross-coupling reactions are
synthesized using ruthenium-catalyzed olefin cross-metathesis of 1-propenyl pinacol …

Selected synthetic strategies to spirocyclics

S Kotha, AC Deb, K Lahiri, E Manivannan - Synthesis, 2009 - thieme-connect.com
The design and synthesis of spirocycles is a challenging task because it involves the
creation of a quaternary center, which itself is considered to be one of the most difficult tasks …

Formation of medium-ring heterocycles by diene and enyne metathesis

SK Chattopadhyay, S Karmakar, T Biswas… - Tetrahedron, 2007 - Elsevier
The word 'metathesis' describes the interchange of covalent bonds between two molecules.
In olefin chemistry, it refers to the redistribution of alkylidene moieties between two alkenes …

Synthesis of symmetrical trisubstituted olefins by cross metathesis

AK Chatterjee, DP Sanders, RH Grubbs - Organic letters, 2002 - ACS Publications
Trisubstituted alkenes have been prepared via intermolecular olefin cross-metathesis (CM)
between α-olefins and symmetrically 1, 1-disubstituted olefins using an imidazolylidene …

Rongalite: a useful green reagent in organic synthesis

S Kotha, P Khedkar - Chemical Reviews, 2012 - ACS Publications
Rongalite, also called Rongalit (Rongal-registered trademark of BASF), is sodium
hydroxymethanesulfinate dihydrate, which is represented by the chemical formula …

Design and synthesis of spirocycles

S Kotha, NR Panguluri, R Ali - European Journal of Organic …, 2017 - Wiley Online Library
In this account we disclose a variety of simple strategies demonstrated in our laboratory in
the last two decades for the assembly of diverse and intricate molecular frameworks …

The building block approach to unusual α-amino acid derivatives and peptides

S Kotha - Accounts of chemical research, 2003 - ACS Publications
The building block approach was identified as a useful alternative to the commonly used
Bücherer− Berg method for the preparation of cyclic unusual α-amino acid derivatives. The …