While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Over the last 15 years, a plethora of research has provided major insights into the structure
and function of hydrogenase enzymes. This has led to the important development of …

Hydrogenases are the most active molecular catalysts for hydrogen production and uptake,,
and could therefore facilitate the development of new types of fuel cell,,. In [FeFe] …

This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

With the price-competitiveness of solar and wind power, hydrogen technologies may be
game changers for a cleaner, defossilized, and sustainable energy future. H2 can indeed be …

Cobaloximes have been examined as electrocatalysts for proton reduction in nonaqueous
solvent in the presence of triethylammonium chloride.[CoIII (dmgH) 2pyCl], working at …

An X-ray crystallographic refinement of the H-cluster of [FeFe]-hydrogenase from Clostridium
pasteurianum has been carried out to close-to atomic resolution and is the highest …

The extraordinary potential of hydrogen as a clean and sustainable fuel has sparked the
interest of the scientific community to find environmentally friendly methods for its production …

[FeFe]-hydrogenases are to date the only enzymes for which it has been demonstrated that
the native inorganic binuclear cofactor of the active site Fe2 (adt)(CO) 3 (CN) 2 (adt …

A short non-exhaustive overview of hexacarbonyl dithiolate di-iron species and of their
substituted derivatives relevant to the chemistry of the di-iron sub-site of the hydrogenase …