The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity

N Lehnert, E Kim, HT Dong, JB Harland… - Chemical …, 2021 - ACS Publications
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications

S Sun, J Choe, J Cho - Chemical Science, 2024 - pubs.rsc.org
In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide
range of physiological and pathological processes. Given the significance of NO, there has …

The impact of simulation sequencing on perceived clinical decision making

A Woda, J Hansen, M Paquette, R Topp - Nurse education in practice, 2017 - Elsevier
An emerging nursing education trend is to utilize simulated learning experiences as a
means to optimize competency and decision making skills. The purpose of this study was to …

A Series of Iron Nitrosyl Complexes {Fe–NO}6–9 and a Fleeting {Fe–NO}10 Intermediate en Route to a Metalacyclic Iron Nitrosoalkane

M Keilwerth, J Hohenberger… - Journal of the …, 2019 - ACS Publications
Iron–nitrosyls have fascinated chemists for a long time due to the noninnocent nature of the
NO ligand that can exist in up to five different oxidation and spin states. Coordination to an …

Photoinduced NO and HNO Production from Mononuclear {FeNO}6 Complex Bearing a Pendant Thiol

CK Chiang, KT Chu, CC Lin, SR Xie… - Journal of the …, 2020 - ACS Publications
Light triggers the formation of HNO from a metal–nitrosyl species, facilitated by an
intramolecular pendant thiol proton. Two {FeNO} 6 complexes (the Enemark–Felthan …

A Nonheme, High-Spin {FeNO}8 Complex that Spontaneously Generates N2O

AM Confer, AC McQuilken, H Matsumura… - Journal of the …, 2017 - ACS Publications
One-electron reduction of [Fe (NO)-(N3PyS)] BF4 (1) leads to the production of the
metastable nonheme {FeNO} 8 complex,[Fe (NO)(N3PyS)](3). Complex 3 is a rare example …

Spectroscopic characterization of a diferric mycobacterial hemerythrin-like protein with unprecedented reactivity toward nitric oxide

T Albert, P Moënne-Loccoz - Journal of the American Chemical …, 2022 - ACS Publications
Hemerythrin-like proteins (HLPs) are broadly distributed across taxonomic groups and
appear to play highly diverse functional roles in prokaryotes. Mycobacterial HLPs contribute …

Rearrangement regulated cysteine fluorescent probe for cellular oxidative stress evaluation induced by copper (II)

N Zhou, F Huo, Y Yue, K Ma, C Yin - Chinese Chemical Letters, 2020 - Elsevier
Cysteine (Cys) plays an important role in regulating cellular redox balance. But due to the
constant changes in the concentration of Cys in organisms, fast response sensors are urgent …

Smart dual T 1 MRI-optical imaging agent based on a rhodamine appended Fe (III)-catecholate complex

D Maheshwaran, T Nagendraraj, TS Balaji… - Dalton …, 2020 - pubs.rsc.org
A rhodamine appended Fe (III)-catecholate complex Fe (RhoCat) 3 is reported as a smart
dual-modal T1 MRI-optical imaging probe. The high spin Fe (III) coordination sphere and …

A Nonheme Mononuclear {FeNO}7 Complex that Produces N2O in the Absence of an Exogenous Reductant

A Dey, JB Gordon, T Albert, S Sabuncu… - Angewandte …, 2021 - Wiley Online Library
A new nonheme iron (II) complex, FeII (Me3TACN)((OSiPh2) 2O)(1), is reported. Reaction of
1 with NO (g) gives a stable mononitrosyl complex Fe (NO)(Me3TACN)((OSiPh2) 2O)(2) …