Oxidative addition of aryl electrophiles to a prototypical nickel (0) complex: mechanism and structure/reactivity relationships

S Bajo, G Laidlaw, AR Kennedy, S Sproules… - …, 2017 - ACS Publications
Detailed kinetic studies of the reaction of a model Ni0 complex with a range of aryl
electrophiles have been conducted. The reactions proceed via a fast ligand exchange pre …

Collaboration as a Key to Advance Capabilities for Earth-Abundant Metal Catalysis

PJ Chirik, KM Engle, EM Simmons… - … Process Research & …, 2023 - ACS Publications
Earth-abundant metal (EAM) catalysis can have profound impact in the pharmaceutical
industry in terms of sustainability and cost improvements from replacing precious metals like …

Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)

JA Cruz-Navarro, A Sánchez-Mora, JS Serrano-García… - Catalysts, 2024 - mdpi.com
The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant
growth due to the price increase of noble metals and their scarce abundance. As a result …

Reactions of nickel (0) with organochlorides, organobromides, and organoiodides: mechanisms and structure/reactivity relationships

ME Greaves, ELBJ Humphrey… - Catalysis Science & …, 2021 - pubs.rsc.org
The reactions of nickel (0) complexes with organohalides have been reviewed. The review
is divided according to the class of ligand that is present on nickel: phosphine, N …

Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis

L Nattmann, J Cornella - Organometallics, 2020 - ACS Publications
Sixteen-electron Ni (0) complexes bearing trans-stilbene derivative ligands have been
shown to display a high degree of stability toward oxidation in the solid state. A structural …

Nickel‐Catalyzed Synthesis of N‐(Hetero)aryl Carbamates from Cyanate Salts and Phenols Activated with Cyanuric Chloride

I Dindarloo Inaloo, M Esmaeilpour, S Majnooni… - …, 2020 - Wiley Online Library
A simple and efficient domino reaction has been designed and employed for the one‐pot
synthesis of N‐(hetero) aryl carbamates through the reaction between alcohols and in‐situ …

A Decarboxylative Cross-Coupling Platform To Access 2-Heteroaryl Azetidines: Building Blocks with Application in Medicinal Chemistry

JT Brewster, SD Randall, J Kowalski, C Cruz… - Organic …, 2022 - ACS Publications
Photoredox-transition metal dual catalysis provides a unique platform for constructing sp 3-
rich chemical matter. Here, we report a nickel-catalyzed cross-coupling of commercially …

Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent

X Guo, H Dang, SR Wisniewski, EM Simmons - Organometallics, 2022 - ACS Publications
The development of a Ni-catalyzed Suzuki–Miyaura cross-coupling that utilizes a weak
amine base and performs optimally with water as a cosolvent is reported. The aqueous …

Nickel‐Catalyzed Mono‐Selective α‐Arylation of Acetone with Aryl Chlorides and Phenol Derivatives

SA Derhamine, T Krachko, N Monteiro… - Angewandte …, 2020 - Wiley Online Library
The challenging nickel‐catalyzed mono‐α‐arylation of acetone with aryl chlorides, pivalates,
and carbamates has been achieved for the first time. A nickel/Josiphos‐based catalytic …

Recent developments in nickel catalyzed Suzuki-Miyaura C–C cross-coupling reaction

S Datta, A Chandra, S Bhattacharya - Inorganica Chimica Acta, 2024 - Elsevier
The palladium-catalyzed Csingle bondC cross-coupling between aryl halides and aryl
boronic acids was first reported by Prof. Akira Suzuki in 1979. Since then, such type of …