Monofluorination of organic compounds: 10 years of innovation

PA Champagne, J Desroches, JD Hamel… - Chemical …, 2015 - ACS Publications
Taking into account the vast arrays of fluorinated motifs known, 11 this review will be limited
to the monofluorination of organic compounds, ie, synthetic methods allowing the …

Electrophilic selenium catalysis with electrophilic NF reagents as the oxidants

R Guo, L Liao, X Zhao - Molecules, 2017 - mdpi.com
A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short
review offers the overview of recent development in ESC with electrophilic NF reagents as …

Silver-catalyzed ring-opening strategy for the synthesis of β-and γ-fluorinated ketones

H Zhao, X Fan, J Yu, C Zhu - Journal of the American Chemical …, 2015 - ACS Publications
A regioselective synthesis of β-and γ-fluorinated ketones via silver-catalyzed ring opening is
described. A variety of β-and γ-fluorinated ketones are efficiently prepared, respectively …

Visible light-promoted metal-free sp 3-C–H fluorination

JB Xia, C Zhu, C Chen - Chemical Communications, 2014 - pubs.rsc.org
Photoexcited acetophenone can catalyze the fluorination of unactivated C (sp3)–H groups.
While acetophenone, a colorless oil, only has a trace amount of absorption in the visible …

Organoselenium-catalyzed oxidative allylic fluorination with electrophilic N–F reagent

R Guo, J Huang, X Zhao - ACS Catalysis, 2018 - ACS Publications
An efficient route of organoselenium-catalyzed oxidative allylic fluorination has been
developed. In this transformation, bulky electrophilic fluorinating reagent N-fluoro-2, 4, 6 …

Radical fluorination reactions by thermal and photoinduced methods

B Lantaño, A Postigo - Organic & Biomolecular Chemistry, 2017 - pubs.rsc.org
The radical or radical ion-based fluorination reactions of organic compounds will be
presented. These methodologies include fluorination processes accomplished through …

Shielding effect of micelle for highly effective and selective monofluorination of indoles in water

PP Bora, M Bihani, S Plummer, F Gallou… - …, 2019 - Wiley Online Library
Highly selective direct monofluorination of indoles and arenes was developed through an
approach that allows site‐specific solubility of substrate and fluorine source in the micelle …

Recent advances in visible light-mediated fluorination

TT Bui, WP Hong, HK Kim - Journal of Fluorine Chemistry, 2021 - Elsevier
The fluorine motif is one of the most important structures in organic chemistry and medicinal
chemistry, having been employed in many applications including pharmaceuticals …

Regiocontrolled allylic functionalization of internal alkene via selenium-π-acid catalysis guided by boron substitution

L Yang, Y Liu, WX Fan, DH Tan, Q Li, H Wang - Chemical Science, 2022 - pubs.rsc.org
The selenium-π-acid-catalysis has received increasing attention as a powerful tool for olefin
functionalization, but the regioselectivity is often problematic. Reported herein is a selenium …

Catalytic 1, 1-diazidation of alkenes

W Qiu, L Liao, X Xu, H Huang, Y Xu, X Zhao - Nature communications, 2024 - nature.com
Compared to well-developed catalytic 1, 2-diazidation of alkenes to produce vicinal
diazides, the corresponding catalytic 1, 1-diazidation of alkenes to yield geminal diazides …