[Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds
K Ding, H Wu, Z Hu, J Wang, Y Wu, H Yu - Small, 2023 - Wiley Online Library
Salt‐inclusion chalcogenides (SICs) have been receiving widespread attention due to their
large second harmonic generation (SHG) responses and wide bandgaps, however most of …
large second harmonic generation (SHG) responses and wide bandgaps, however most of …
Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)
X Lian, ZT Lu, WD Yao, SH Yang, W Liu… - Inorganic …, 2021 - ACS Publications
Investigations of inorganic compounds with mixed anions have drawn much attention. Here,
three oxysulfides, Sm3NbS3O4 (1), Gd3NbS3O4 (2), and Dy3NbS3O4 (3), are obtained by …
three oxysulfides, Sm3NbS3O4 (1), Gd3NbS3O4 (2), and Dy3NbS3O4 (3), are obtained by …
Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides
MY Ran, SH Zhou, BX Li, XT Wu, H Lin… - Chemistry of …, 2024 - ACS Publications
Oxychalcogenides have become notable contenders for infrared nonlinear optical (IR NLO)
applications because of their diverse heteroanionic functional motifs. However, while the …
applications because of their diverse heteroanionic functional motifs. However, while the …
Synthesis of Non-centrosymmetric, Metastable Rare-Earth Oxysulfides by Anionic Redox Topochemistry
Intercalation/deintercalation reactions enable introduction/removal of intercalants without
destructive structure transformation of host lattices. They are among the most versatile ways …
destructive structure transformation of host lattices. They are among the most versatile ways …
Heteroanionic [VO x S 4− x] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals
S Zhang, L Dong, B Xu, H Chen, H Huo… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Tetrahedral groups can possess a wide bandgap and large second harmonic generation
(SHG) response in nonlinear optical (NLO) materials; however, they usually exhibit a small …
(SHG) response in nonlinear optical (NLO) materials; however, they usually exhibit a small …
Anion redox as a means to derive layered manganese oxychalcogenides with exotic intergrowth structures
Topochemistry enables step-by-step conversions of solid-state materials often leading to
metastable structures that retain initial structural motifs. Recent advances in this field …
metastable structures that retain initial structural motifs. Recent advances in this field …
Versatile Interplay of Chalcogenide and Dichalcogenide Anions in the Thiovanadate Ba7S(VS3O)2(S2)3 and Its Selenide Derivatives: Elaboration and DFT Meta …
Oxychalcogenides are emerging as promising alternative candidates for a variety of
applications including for energy. Only few phases among them show the presence of Q–Q …
applications including for energy. Only few phases among them show the presence of Q–Q …
La4Ga2S8O3: A Rare-Earth Gallium Oxysulfide with Disulfide Ions
H Yan, K Fujii, H Kabbour, A Chikamatsu… - Inorganic …, 2023 - ACS Publications
Band gap engineering using multiple anions is an established approach to novel
photocatalysts that exhibit suitable band gap energies for water splitting and high …
photocatalysts that exhibit suitable band gap energies for water splitting and high …
Designing Visible-Light Photoactive Thioapatites Using Thiovanadate Groups: The Ba5(VO4−αSα)3X (X = F, Cl, I) Phases
The new thioapatite Ba5 (VO4− αSα) 3X (X= F, Cl, I) series of compounds was prepared and
characterized. Compared to known apatite phases built from unconnected vanadate VO4 …
characterized. Compared to known apatite phases built from unconnected vanadate VO4 …
Homovalent cation substitutions leading to new lithium-containing La3CuSiS7 family members having chiral, uniaxial structures and exhibiting second-and third …
AJ Craig, JB Cho, SH Shin, SH Ha, SS Stoyko… - Journal of Alloys and …, 2022 - Elsevier
Eighteen isotypic, lithium-containing rare-earth sulfides, crystallizing in the chiral, polar, and
noncentrosymmetric space group P6 3 with the La 3 CuSiS 7-structure type have been …
noncentrosymmetric space group P6 3 with the La 3 CuSiS 7-structure type have been …