Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials
FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …
and applications of metal complexes containing heteroallylic ligands such as amidinates …
Interdigitated hydrogen bonds: electrophile activation for covalent capture and fluorescence turn-on detection of cyanide
Hydrogen-bonding promoted covalent modifications are finding useful applications in small-
molecule chemical synthesis and detection. We have designed a xanthene-based …
molecule chemical synthesis and detection. We have designed a xanthene-based …
Direct functionalization of unactivated C–H bonds catalyzed by group 3–5 metal alkyl complexes
H Tsurugi, K Yamamoto, H Nagae, H Kaneko… - Dalton …, 2014 - pubs.rsc.org
This perspective summarizes direct C–H bond functionalization reactions catalyzed by
group 3–5 metal alkyl complexes. Metal–carbon bonds of group 3–5 metals have potentially …
group 3–5 metal alkyl complexes. Metal–carbon bonds of group 3–5 metals have potentially …
Highly active dinuclear titanium (IV) complexes for the catalytic formation of a carbon–heteroatom bond
J Bhattacharjee, A Harinath, I Banerjee… - Inorganic …, 2018 - ACS Publications
A series of mononuclear titanium (IV) complexes with the general composition κ3-[R
{NHPh2P (X)} 2Ti (NMe2) 2][R= C6H4, X= Se (3b); R= trans-C6H10, X= S (4a), Se (4b)] and …
{NHPh2P (X)} 2Ti (NMe2) 2][R= C6H4, X= Se (3b); R= trans-C6H10, X= S (4a), Se (4b)] and …
Oxidant-free direct coupling of internal alkynes and 2-alkylpyridine via double C− H activations by alkylhafnium complexes
H Tsurugi, K Yamamoto, K Mashima - Journal of the American …, 2011 - ACS Publications
We have developed a novel oxidant-free direct cross-coupling reaction of 2, 6-lutidine and
internal alkynes leading to five-membered carbocyclic compounds mediated by …
internal alkynes leading to five-membered carbocyclic compounds mediated by …
Imidazolin-2-iminato ligand-supported titanium complexes as catalysts for the synthesis of urea derivatives
The reactions of tetrakis (dimethylamido) titanium (IV)[Ti (NMe2) 4] with three different
imidazolin-2-imines (ImRNH; R= tert-butyl (t Bu), mesityl (Mes), and 2, 6-diisopropylphenyl …
imidazolin-2-imines (ImRNH; R= tert-butyl (t Bu), mesityl (Mes), and 2, 6-diisopropylphenyl …
Hydroamination of carbodiimides, isocyanates, and isothiocyanates by a bis (phosphinoselenoic amide) supported titanium (IV) complex
The hydroamination of heterocumulenes such as carbodiimides, isocyanates, and
isothiocyanates by a bis (phosphinoselenoic amide) supported titanium (IV) complex as a …
isothiocyanates by a bis (phosphinoselenoic amide) supported titanium (IV) complex as a …
Reactions of Group 4 Metallocene Complexes with Mono‐and Diphenylacetonitrile: Formation of Unusual Four‐and Six‐Membered Metallacycles
L Becker, VV Burlakov, P Arndt… - … A European Journal, 2013 - Wiley Online Library
Reactions of Group 4 metallocene alkyne complexes [Cp′ 2M (η2‐Me3SiC2SiMe3)](1: M=
Zr, Cp′= Cp*= η5‐pentamethylcyclopentadienyl; 2 a: M= Ti, Cp′= Cp*, and 2 b: M= Ti …
Zr, Cp′= Cp*= η5‐pentamethylcyclopentadienyl; 2 a: M= Ti, Cp′= Cp*, and 2 b: M= Ti …
Phenoxyamidine Zn and Al complexes: synthesis, characterization, and use in the ring-opening polymerization of lactide
F Chotard, R Lapenta, A Bolley… - …, 2019 - ACS Publications
Herein, we report the synthesis of new ditopic ligands, which consist of a phenoxy group and
N, N, N′-trisubstituted amidines linked by a methylene spacer (L1–L4). Their coordination …
N, N, N′-trisubstituted amidines linked by a methylene spacer (L1–L4). Their coordination …
Hydroboration, Cyanosilylation, and Sequential Cyanosilylation and Hydroboration of Carbonyl Compounds in the Presence of a TiIV Amido Complex as an Efficient …
A Harinath, J Bhattcharjee, KR Gorantla… - European Journal of …, 2018 - Wiley Online Library
Catalytic hydroboration and cyanosilylation of a wide range of aldehydes and ketones, with
pinacolborane (4, 4, 5, 5‐tetramethyl‐1, 3, 2‐dioxaborolane) and trimethylsilyl cyanide …
pinacolborane (4, 4, 5, 5‐tetramethyl‐1, 3, 2‐dioxaborolane) and trimethylsilyl cyanide …