Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis

R Saha, B Mondal, PS Mukherjee - Chemical Reviews, 2022 - ACS Publications
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Encapsulated metal nanoparticles for catalysis

C Gao, F Lyu, Y Yin - Chemical Reviews, 2020 - ACS Publications
Metal nanoparticles have drawn great attention in heterogeneous catalysis. One challenge
is that they are easily deactivated by migration-coalescence during the catalysis process …

Metal-organic framework-based catalysts for hydrogen production from liquid-phase chemical hydrides

Q Yao, X Zhang, ZH Lu, Q Xu - Coordination Chemistry Reviews, 2023 - Elsevier
Hydrogen is a clean, sustainable, and efficient energy carrier. However, the safe and
controllable storage and evolution of hydrogen for practical applications remain challenging …

State of the art and prospects in metal–organic framework (MOF)-based and MOF-derived nanocatalysis

Q Wang, D Astruc - Chemical reviews, 2019 - ACS Publications
Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers,
are a major part of nanomaterials science, and their role in catalysis is becoming central …

Organo-macrocycle-containing hierarchical metal–organic frameworks and cages: design, structures, and applications

Y Liang, E Li, K Wang, ZJ Guan, H He… - Chemical Society …, 2022 - pubs.rsc.org
Developing hierarchical ordered systems is challenging. Using organo-macrocycles to
construct metal–organic frameworks (MOFs) and porous coordination cages (PCCs) …

Advances in supramolecular host-mediated reactivity

M Morimoto, SM Bierschenk, KT Xia, RG Bergman… - Nature Catalysis, 2020 - nature.com
Since the trailblazing discoveries of Lehn, Cram and Pedersen, supramolecular chemistry
has established itself as a cornerstone of organic chemistry. Supramolecular hosts offer …

Nanopore‐supported metal nanocatalysts for efficient hydrogen generation from liquid‐phase chemical hydrogen storage materials

Q Sun, N Wang, Q Xu, J Yu - Advanced Materials, 2020 - Wiley Online Library
Hydrogen has emerged as an environmentally attractive fuel and a promising energy carrier
for future applications to meet the ever‐increasing energy challenges. The safe and efficient …

[HTML][HTML] A cage-on-MOF strategy to coordinatively functionalize mesoporous MOFs for manipulating selectivity in adsorption and catalysis

Y Liang, X Yang, X Wang, ZJ Guan, H Xing… - Nature …, 2023 - nature.com
Functionalizing porous materials with capping agents generates hybrid materials with
enhanced properties, while the challenge is how to improve the selectivity and maintain the …

Catalytic reactions within the cavity of coordination cages

Y Fang, JA Powell, E Li, Q Wang, Z Perry… - Chemical Society …, 2019 - pubs.rsc.org
Natural enzymes catalyze reactions in their substrate-binding cavities, exhibiting high
specificity and efficiency. In an effort to mimic the structure and functionality of enzymes …

Noble-metal-free nanocatalysts for hydrogen generation from boron-and nitrogen-based hydrides

Q Yao, Y Ding, ZH Lu - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
Hydrogen has attracted much attention as a globally accepted clean energy carrier.
Currently, the search for safe and efficient hydrogen storage materials is one of the most …