Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Abstract (Pentamethylcyclopentadienyl) rhodium (RhCp*)‐catalyzed C H transformations
have emerged as a prosperous field in C H bond activation. Recent advances in this area …

C− H functionalization represents a paradigm shift from the standard logic of organic
synthesis. Instead of focusing on orchestration of selective reactions at functional groups, the …

Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …

Ever‐evolving catalyst advances in synthetic protocols using water as a reaction medium
have enriched the understanding of sustainable organic chemistry. Because conventional …

The linear or branched allyl moieties on aromatic rings are well-known as ubiquitous
structural motifs found in a range of natural products and medicinally relevant molecules …

Reported herein is the iridium-catalyzed direct amidation of unactivated sp3 C–H bonds.
With sulfonyl and acyl azides as the amino source, the amidation occurs efficiently under …

The Co (III)-catalyzed direct C–H amidation of arenes has been developed using O-
acylcarbamates as a convenient amino source. This reaction proceeded in high efficiency …

C–H functionalisation promises a paradigm shift in synthetic planning. However, the
additional steps often required to install and remove directing groups currently detract from …

Abstract Though Cp* Rh (iii) complexes are prominent and versatile catalysts for C–H bond
functionalization reactions, catalytic stereocontrol is difficult due to the lack of vacant …