Activation and conversion of alkanes in the confined space of zeolite-type materials

P Del Campo, C Martínez, A Corma - Chemical Society Reviews, 2021 - pubs.rsc.org
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …

Selective Oxidative Dehydrogenation of Ethane and Propane over Copper‐Containing Mordenite: Insights into Reaction Mechanism and Product Protection

MA Artsiusheuski, R Verel… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Copper (II)‐containing mordenite (CuMOR) is capable of activation of C− H bonds
in C1‐C3 alkanes, albeit there are remarkable differences between the functionalization of …

Speciation of Cu-Oxo clusters in ferrierite for selective oxidation of methane to methanol

L Tao, I Lee, R Khare, A Jentys, JL Fulton… - Chemistry of …, 2022 - ACS Publications
Cu-oxo nanoclusters in Cu-exchanged zeolites oxidize methane to methanol via a three-
step process. Cu-exchanged ferrierite shows high reactivity to this selective oxidation at both …

Continuous synthesis of methanol from methane and steam over copper-mordenite

YR Jeong, H Jung, J Kang, JW Han, ED Park - ACS Catalysis, 2021 - ACS Publications
One-step methane-to-methanol conversion is a “dream reaction” for chemists. In this Letter,
continuous direct conversion of methane into methanol with steam under mild conditions …

Reactivity of Methoxy species towards Methylation and Oligomerization in Cu-Zeolite systems

BG Solemsli, IC Berdiell, S Prodinger, K Kvande… - Catalysis Today, 2024 - Elsevier
Ethylene, propylene, and benzene were investigated as molecules for extracting methoxy
intermediate species formed during the cyclic partial oxidation of methane in Cu-exchanged …

Solid-State NMR Probe Molecules for Catalysts and Adsorbents: Concepts, Quantification, Accessibility, and Spatial Distribution

M Dyballa - Energy & Fuels, 2023 - ACS Publications
The application of probe molecules is the state-of-the-art method to quantitatively determine
accessibility and spatial distribution of catalytically active sites on solid materials. Knowing …

Cu oxo nanoclusters for direct oxidation of methane to methanol: formation, structure and catalytic performance

L Tao, I Lee, M Sanchez-Sanchez - Catalysis Science & Technology, 2020 - pubs.rsc.org
Cu oxo nanoclusters hosted in microporous solids have emerged in the past decades as
promising materials for catalyzing the selective conversion of methane to methanol. In this …

Methane-selective oxidation to methanol and ammonia selective catalytic reduction of NOx over monolithic Cu/SSZ-13 catalysts: Are hydrothermal stability and active …

C Zhou, H Zhang, L Yang, D Wu, S He, H Yang… - Fuel, 2022 - Elsevier
This study investigated and compared the reactivities of NH 3-SCR and methane-to-
methanol reactions over the monolithic Cu/SSZ-13 catalysts with different zeolite crystal …

Roles of Acidic Proton for Fe-Containing Zeolite in Direct Oxidation of Methane

P Xiao, H Toyoda, Y Wang, K Nakamura, S Bekhti… - ACS …, 2024 - ACS Publications
Fe-containing zeolite catalysts are active in N2O decomposition and direct oxidation of
unreactive methane. Except for the well-known ability that acid sites realize the subsequent …

Direct methane to methanol stepwise conversion over Cu-oxo species in zeolites–Insights on the Cu-zeolite activation in air or helium from in situ UV-Vis analyses

RJ Passini, M Picinini, JMC Bueno… - Molecular …, 2022 - Elsevier
Among the plentiful scientific research focused to find new routes to substitute stronger
unsustainable chemical processes, the direct conversion (DC) of methane to methanol …