Lewis acids: from conventional homogeneous to green homogeneous and heterogeneous catalysis

A Corma, H Garcia - Chemical Reviews, 2003 - ACS Publications
Acid-catalyzed reactions are by far the most numerous and best-studied reaction type, 1-5 in
which organic functional groups undergo an array of different transformations with …

Tailored crystalline microporous materials by post-synthesis modification

V Valtchev, G Majano, S Mintova… - Chemical Society …, 2013 - pubs.rsc.org
Crystalline microporous solids are an important class of inorganic materials with uses in
different areas impacting our everyday lives, namely as catalysts, adsorbents, and ion …

Inorganic solid acids and their use in acid-catalyzed hydrocarbon reactions

A Corma - Chemical reviews, 1995 - ACS Publications
Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions Page 1 Chem.
Rev. 1995, 95, 559-614 559 Inorganic Solid Acids and Their Use in Acid-Catalyzed …

Identification and characterization of surface hydroxyl groups by infrared spectroscopy

K Hadjiivanov - Advances in Catalysis, 2014 - Elsevier
Surface hydroxyl groups are active centers in many catalytic reactions and can play an
important role during catalyst preparation. In this chapter, the application of infrared …

On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis …

M Ravi, VL Sushkevich, JA van Bokhoven - Chemical Science, 2021 - pubs.rsc.org
Lewis acidic aluminum in zeolites, particularly acidity that is inherent to the framework, is an
indeterminate concept. A fraction of framework aluminum changes geometry to octahedral …

The acidity of zeolites: concepts, measurements and relation to catalysis: a review on experimental and theoretical methods for the study of zeolite acidity

EG Derouane, JC Vedrine, RR Pinto, PM Borges… - Catalysis …, 2013 - Taylor & Francis
In this article, we considered all aspects of acidity (nature of acid sites, strength, density, etc.)
in solid catalysts and in zeolites in particular. After reminding the definition of acidity in liquid …

Progress toward understanding zeolite. beta. acidity: an IR and 27Al NMR spectroscopic study

I Kiricsi, C Flego, G Pazzuconi… - The Journal of …, 1994 - ACS Publications
Zeolite ß was prepared with different Si/Al ratios by a hydrothermal method and
dealuminated by leaching with dilute HC1. Samples of ß from the various stages of H-ß …

Perspectives of micro/mesoporous composites in catalysis

J Čejka, S Mintova - Catalysis Reviews, 2007 - Taylor & Francis
This article covers the recent development in the remarkably growing field of synthesis,
characterization and particularly catalytic investigation of zeolite‐based materials combining …

Design of a Metal‐Promoted Oxide Catalyst for the Selective Synthesis of Butadiene from Ethanol

VL Sushkevich, II Ivanova, VV Ordomsky… - …, 2014 - Wiley Online Library
Abstract The synthesis of buta‐1, 3‐diene from ethanol has been studied over metal‐
containing (M= Ag, Cu, Ni) oxide catalysts (MOx= MgO, ZrO2, Nb2O5, TiO2, Al2O3) …

Catalytic dehydration of ethanol over post-treated ZSM-5 zeolites

H Xin, X Li, Y Fang, X Yi, W Hu, Y Chu, F Zhang… - Journal of catalysis, 2014 - Elsevier
Microporous ZSM-5 zeolite was post-treated by desilication with sodium hydroxide,
dealumination with oxalic acid, or both of them in a sequential way to finely tune the zeolite …