Green chemistry in the synthesis of pharmaceuticals

S Kar, H Sanderson, K Roy, E Benfenati… - Chemical …, 2021 - ACS Publications
The principles of green chemistry (GC) can be comprehensively implemented in green
synthesis of pharmaceuticals by choosing no solvents or green solvents (preferably water) …

Borrowing hydrogen for organic synthesis

BG Reed-Berendt, DE Latham, MB Dambatta… - ACS Central …, 2021 - ACS Publications
Borrowing hydrogen is a process that is used to diversify the synthetic utility of commodity
alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive …

3d-Metal catalyzed N-and C-alkylation reactions via borrowing hydrogen or hydrogen autotransfer

T Irrgang, R Kempe - Chemical reviews, 2018 - ACS Publications
The conservation of our element resources is a fundamental challenge of mankind. The
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …

Borrowing hydrogen amination reactions: a complex analysis of trends and correlations of the various reaction parameters

E Podyacheva, OI Afanasyev, DV Vasilyev… - ACS …, 2022 - ACS Publications
Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to
create single C–N bonds, starting from stable and readily available substrates: amines and …

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

S Elangovan, J Neumann, JB Sortais, K Junge… - Nature …, 2016 - nature.com
Borrowing hydrogen (or hydrogen autotransfer) reactions represent straightforward and
sustainable C–N bond-forming processes. In general, precious metal-based catalysts are …

Intermetallic compounds: promising inorganic materials for well-structured and electronically modified reaction environments for efficient catalysis

S Furukawa, T Komatsu - Acs Catalysis, 2017 - ACS Publications
An overview of the catalytic properties of intermetallic compounds has been made to provide
a comprehensive understanding regarding (1) what intermetallic catalysts can do,(2) their …

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

Q Yang, Q Wang, Z Yu - Chemical Society Reviews, 2015 - pubs.rsc.org
Transition metal-catalyzed substitution of alcohols by N-nucleophiles (or N-alkylation of
amines and related compounds with alcohols) avoids the use of alkylating agents by means …

Catalysis with colloidal ruthenium nanoparticles

MR Axet, K Philippot - Chemical reviews, 2020 - ACS Publications
This review provides a synthetic overview of the recent research advancements addressing
the topic of catalysis with colloidal ruthenium metal nanoparticles through the last five years …

Atomic-Level Asymmetric Tuning of the Co1–N3P1 Catalyst for Highly Efficient N-Alkylation of Amines with Alcohols

H Liu, L Tian, Z Zhang, L Wang, J Li… - Journal of the …, 2024 - ACS Publications
Despite the extensive development of non-noble metals for the N-alkylation of amines with
alcohols, the exploitation of catalysts with high selectivity, activity, and stability still faces …

Bio-based amines through sustainable heterogeneous catalysis

M Pelckmans, T Renders, S Van de Vyver, BF Sels - Green Chemistry, 2017 - pubs.rsc.org
The production of amines from biomass is a growing field of interest. Particularly the
amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent …