Silver is a less expensive noble metal. Superior alkynophilicity due to π-coordination with
the carbon–carbon triple bond makes silver salts ideal catalysts for alkyne-based organic …

Described herein is an organocatalytic enantioselective desymmetrizing cycloisomerization
of arylsulfonyl‐protected ynamide cyclohexanones, representing the first metal‐free …

The first and asymmetric total synthesis of longeracinphyllin A, a hexacyclic Daphniphyllum
alkaloid, has been accomplished. A tetracyclic intermediate was prepared through silver …

A synthetic approach to paxilline indole diterpenes is described. The route to the pentacyclic
core relies on a new regioselective alkenylation of ketones and a tandem radical addition …

Covers all the aspects of the recent achievements in silver catalyzed reactions Silver
catalysis has emerged as a powerful tool in the field of organic synthesis. This …

Enol ethers are a fascinating product class and valuable building blocks with versatile
reactivities and synthetic applications. With the emergence of silyl enol ethers, the chemistry …

A novel catalytic cyclization reaction of alkynyl α-ketoanilide was developed by utilizing the
[1, 2]-phospha-Brook rearrangement. This reaction involves the generation of an amide …

The silver-catalyzed three-component reaction of propargylic amines, carbon dioxide, and N-
iodosuccinimide for the stereoselective synthesis of (E)-iodovinyloxazolidinones was …

Cyclization of silylenolether‐ynesulfonamides proceeds at ambient temperature under mild
reaction conditions under silver catalysis. Bridged compounds were obtained exclusively …

The stereoselective synthesis of aminovinyloxazolidinones based on the electrophilic
amination of a vinyl-silver intermediate, generated by silver-catalyzed carbon dioxide …