Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

Confined crystallization of polymeric materials

RM Michell, AJ Müller - Progress in Polymer Science, 2016 - Elsevier
The interest in confined crystallization has greatly increased with the development and
progress of nanotechnology applications. Polymeric confined crystallization has been …

50th Anniversary Perspective: Functional Nanoparticles from the Solution Self-Assembly of Block Copolymers

U Tritschler, S Pearce, J Gwyther, GR Whittell… - …, 2017 - ACS Publications
This Perspective outlines recent advances concerning the formation and potential uses of
block copolymer micelles, a class of soft-matter-based nanoparticles of growing importance …

Monodisperse cylindrical micelles by crystallization-driven living self-assembly

JB Gilroy, T Gädt, GR Whittell, L Chabanne… - Nature …, 2010 - nature.com
Non-spherical nanostructures derived from soft matter and with uniform size—that is,
monodisperse materials—are of particular utility and interest, but are very rare outside the …

Crystallization assisted self-assembly of semicrystalline block copolymers

WN He, JT Xu - Progress in Polymer Science, 2012 - Elsevier
The self-assembly of block copolymers (BCPs) in the presence of crystallization as the
second driving force is reviewed, for BCPs in the bulk, thin films, single crystals and micelles …

Uniform Biodegradable Fiber-Like Micelles and Block Comicelles via “Living” Crystallization-Driven Self-Assembly of Poly(l-lactide) Block Copolymers: The …

Y He, JC Eloi, RL Harniman… - Journal of the …, 2019 - ACS Publications
Fiber-like micelles based on biodegradable and biocompatible polymers exhibit
considerable promise for applications in nanomedicine, but until recently no convenient …

Aqueous polymerization-induced self-assembly for the synthesis of ketone-functionalized nano-objects with low polydispersity

W Zhou, Q Qu, Y Xu, Z An - ACS Macro Letters, 2015 - ACS Publications
Efficient synthesis of functionalized, uniform polymer nano-objects in water with controlled
morphologies in one step and at high concentrations is extremely attractive, from …

[HTML][HTML] Confinement effects on polymer crystallization: From droplets to alumina nanopores

RM Michell, I Blaszczyk-Lezak, C Mijangos, AJ Müller - Polymer, 2013 - Elsevier
We review previous works on polymer confined crystallization employing strategies that
allow confinement to go from the micron to the nanometer scale: droplets, blends, block …

Micellar Morphologies of Poly(ε-caprolactone)-b-poly(ethylene oxide) Block Copolymers in Water with a Crystalline Core

ZX Du, JT Xu, ZQ Fan - Macromolecules, 2007 - ACS Publications
The self-assembly of poly (ε-caprolactone)-b-poly (ethylene oxide) block copolymers (PCL n
PEO44 and PCL n PEO113) with narrow polydispersity in aqueous medium was studied …

Complex and Hierarchical 2D Assemblies via Crystallization-Driven Self-Assembly of Poly(l-lactide) Homopolymers with Charged Termini

X He, Y He, MS Hsiao, RL Harniman… - Journal of the …, 2017 - ACS Publications
Poly (l-lactide)(PLLA)-based nanoparticles have attracted much attention with respect to
applications in drug delivery and nanomedicine as a result of their biocompatibility and …