Post‐metallocenes in the industrial production of polyolefins

MC Baier, MA Zuideveld… - Angewandte Chemie …, 2014 - Wiley Online Library
Research on “post‐metallocene” polymerization catalysis ranges methodologically from
fundamental mechanistic studies of polymerization reactions over catalyst design to material …

Fluoride ion complexation and sensing using organoboron compounds

CR Wade, AEJ Broomsgrove, S Aldridge… - Chemical …, 2010 - ACS Publications
Fluoride is often added to drinking water and toothpaste because of its beneficial effects in
dental health. It is also administered in the treatment of osteoporosis. 1 While the beneficial …

Noncoordinating anions—fact or fiction? A survey of likely candidates

I Krossing, I Raabe - Angewandte Chemie International Edition, 2004 - Wiley Online Library
Is there anything resembling a truly noncoordinating anion? Would it not be great to be able
to prepare any crazy, beautiful, or simply useful cationic species that one has in mind, or has …

Designs of functional π-electron materials based on the characteristic features of boron

A Wakamiya, S Yamaguchi - Bulletin of the Chemical Society of …, 2015 - academic.oup.com
Boron, a group 13 element, has several characteristic structural and electronic features: 1)
trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence …

Nichtkoordinierende Anionen–Traum oder Wirklichkeit? Eine Übersicht zu möglichen Kandidaten

I Krossing, I Raabe - Angewandte Chemie, 2004 - Wiley Online Library
Gibt es so etwas wie ein wirklich nichtkoordinierendes Anion? Wäre es nicht großartig, jede
verrückte, schöne oder einfach nur nützliche kationische Spezies herstellen zu können, sei …

(Hetero) arene-fused boroles: a broad spectrum of applications

J He, F Rauch, M Finze, TB Marder - Chemical Science, 2021 - pubs.rsc.org
(Hetero) arene-fused boroles are a class of compounds containing a 5-membered boron
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …

Aryl (hydro) boranes: versatile building blocks for boron-doped π-electron materials

A Lorbach, A Hübner, M Wagner - Dalton Transactions, 2012 - pubs.rsc.org
Boron-containing π-conjugated molecules offer a substantial application potential in the field
of organic electronics. During the last decade, aryl (hydro) boranes have established …

Synthesis, structures, and reactivity of weakly coordinating anions with delocalized borate structure: the assessment of anion effects in metallocene polymerization …

J Zhou, SJ Lancaster, DA Walker, S Beck… - Journal of the …, 2001 - ACS Publications
The formation of adducts of tris (pentafluorophenyl) borane with strongly coordinating anions
such as CN-and [M (CN) 4] 2-(M= Ni, Pd) is a synthetically facile route to the bulky, very …

Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to …

J Krebs, A Häfner, S Fuchs, X Guo, F Rauch… - Chemical …, 2022 - pubs.rsc.org
The choice of backbone linker for two ortho-bis-(9-borafluorene) s has a great influence on
the LUMO located at the boron centers and, therefore, the reactivity of the respective …

Group 4 metal complexes for homogeneous olefin polymerisation: a short tutorial review

RA Collins, AF Russell, P Mountford - Applied Petrochemical Research, 2015 - Springer
The discovery of transition metal-catalysed polymerisation of olefins in the 1950s by Ziegler
and Natta was of huge importance. Over the last 30 years, the interest in homogenous …