“Hexagonal Molybdenum Trioxide” Known for 100 Years and Still a Fount of New Discoveries

HJ Lunk, H Hartl, MA Hartl, MJG Fait… - Inorganic …, 2010 - ACS Publications
In 1906, the preparation of “molybdic acid hydrate” was published by Arthur Rosenheim.
Over the past 40 years, a multitude of isostructural compounds, which exist within a wide …

Nanocrystalline transition metal (CoMoO4) prepared by sol gel method: Correlation between powder colors and α/β phase transformations

H Lakhlifi, Y El Jabbar, M Benchikhi, L Er-Rakho… - Inorganic Chemistry …, 2022 - Elsevier
The molybdenum-based binary oxides CoMoO 4 have been synthesized using the sol–gel
method. Thermal analysis (TGA-DTA), X-ray diffraction (XRD), and Rietveld refinement data …

Synthetic approaches for noncentrosymmetric molybdates

DJ Hubbard, AR Johnston, HS Casalongue… - Inorganic …, 2008 - ACS Publications
The use of second-order Jahn− Teller active MoVI centers and chiral organic amines is
discussed as an approach to crystallographic noncentrosymmetry. Several series of …

Hexagonal Mo Bronze: Single Crystal Structures, Electrocatalytic Hydrogen Evolution, and Proton Conductivity

G Premanand, D Jana, PM Unnikrishnan… - Inorganic …, 2024 - ACS Publications
Molybdenum trioxide (MoO3) is a well-known transition metal oxide that has drawn much
attention as a functional material having numerous applications. However, a vast majority of …

Rational Design of Alkali‐Resistant NO Reduction Catalysts using a Stable Hexagonal V‐Doped MoO3 Support for Alkali Trapping

X Liu, J Gao, Y Chen, C Li, J Chen, W Qu… - …, 2018 - Wiley Online Library
To avoid alkali poisoning in the selective catalytic reduction (SCR) of NOx with NH3, it is
desirable to design SCR catalysts with abundant alkali‐trapping sites spatially separated …

Composition space analysis of templated molybdates

JH Nelson, AR Johnston, AN Sarjeant, AJ Norquist - Solid state sciences, 2007 - Elsevier
A systematic investigation of the factors governing reaction product composition and three-
dimensional structure was conducted in the MoO3/H2N (CH2) nNH2/H2O (n= 3–7) systems …

Reinvestigation of hybrid organic–inorganic materials based on molybdate and piperazininum cations: Influence of the synthesis conditions on the chemical …

V Coue, R Dessapt, M Bujoli-Doeuff, M Evain… - Journal of Solid State …, 2008 - Elsevier
The reactivity of the [Mo7O24] 6− anion towards the structure directing-reagent piperazine
(pipz) has been investigated and new synthetic routes to achieve the known (H2pipz) 3 …

Direct hydrothermal synthesis of metal intercalated hexagonal molybdates, M + x Mo6−x/3O18−x (OH)x.yH2O (M …

S Upreti, A Ramanan - Journal of Chemical Sciences, 2003 - Springer
Here we report direct hydrothermal synthesis of a few hexagonal molybdates with
composition, M x/+ Mo 6− x Emphasis>/3/6+ O 18− x (OH) x. yH 2 O (M= Li, Rb, Cs, NH 4) …

Poly [bis (4-aminopyridinium) decaoxotrimolybdate (VI)]

JR Nelson, A Narducci Sarjeant… - … Section E: Structure …, 2006 - journals.iucr.org
The hydrothermally synthesized title compound,{(C5H7N2) 2 [Mo3O10]} n, contains
[Mo3O10] n2n− chains, which are generated through inversion symmetry. An extensive N …

[图书][B] The Extended Family of Hexagonal Molybdenum Oxide

HJ Lunk, H Hartl, TA Frisk, IG Shenderovich, D Mauder… - researchgate.net
Over the last 40 years, a large number of isostructural compounds in the system MoO3-NH3-
H2O have been published. The reported molecular formulae of “hexagonal molybdenum …