Data on the electronic structure and redox, magnetic, luminescent, nonlinear optical and
catalytic properties of tri-and tetranuclear molybdenum and tungsten chalcogenide clusters …

The state-of-the-art and prospects of the development of chemistry of chalcogenide clusters
of Group 5–7 metals of the Periodic Table are discussed. The main structural types, methods …

Functionalized anilines are valuable intermediates for the manufacture of dyes, pigments,
agrochemicals, and pharmaceuticals.[1] Furthermore, they represent key precursors for the …

Azobenzene hydrogenation is catalyzed under moderate conditions by a cuboidal Mo3 (μ3-
S)(μ-S) 3 diamino complex via a cluster catalysis mechanism. Dihydrogen activation by the …

Transition metal cluster chalcogenides with cubane‐type structures are relevant to our
understanding of several industrial and biological catalytic processes. Recent advances in …

Cluster excision of polymeric {Mo3S7Cl4} n phases with chiral phosphane (+)‐1, 2‐bis [(2R,
5R)‐2, 5‐(dimethylphospholan‐1‐yl)] ethane ((R, R)‐Me‐BPE) or with its enantiomer ((S, S) …

Inverse coordination is the formation of metal complexes in which the arrangement of
acceptor and donor sites is opposite to that occurring in conventional coordination …

Cubane-type clusters of formula [Mo3CuS4Cl4 (dmpe) 3](PF6)(4),[Mo3CuS4Br4 (dmpe)
3](PF6)(5), and [W3CuS4Br4 (dmpe) 3](PF6)(6) have been prepared by reacting the …

The molybdenum (IV) cluster hydrides of formula [Mo3S4H3 (diphosphine) 3]+ with
diphosphine= 1, 2-(bis) dimethylphosphinoethane (dmpe) or (+)-1, 2-bis-(2 R, 5 R)-2, 5 …

The [Mo3S4Cl3 (dhmpe) 3] Cl ([1] Cl) cluster has been prepared from [Mo3S7Cl6] 2-and the
water-soluble 1, 2-bis (bis (hydroxymethyl)-phosphino) ethane (dhmpe, L) ligand. The …