Faceted metal and metal oxide nanoparticles: design, fabrication and catalysis
The review addresses new advances in metal, bimetallic, metal oxide, and composite
particles in their nanoregime for facet-selective catalytic applications. The synthesis and …
particles in their nanoregime for facet-selective catalytic applications. The synthesis and …
Operando surface spectroscopy and microscopy during catalytic reactions: from clusters via nanoparticles to meso‐scale aggregates
G Rupprechter - Small, 2021 - Wiley Online Library
Operando characterization of working catalysts, requiring per definitionem the simultaneous
measurement of catalytic performance, is crucial to identify the relevant catalyst structure …
measurement of catalytic performance, is crucial to identify the relevant catalyst structure …
Enhancing both selectivity and coking-resistance of a single-atom Pd1/C3N4 catalyst for acetylene hydrogenation
Selective hydrogenation is an important industrial catalytic process in chemical upgrading,
where Pd-based catalysts are widely used because of their high hydrogenation activities …
where Pd-based catalysts are widely used because of their high hydrogenation activities …
Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes< 10 nm for application in CO oxidation
The catalytic activity of noble-metal nanocrystals is mainly determined by their sizes and the
facets exposed on the surface. For single crystals, it has been demonstrated that the Pd …
facets exposed on the surface. For single crystals, it has been demonstrated that the Pd …
Structure sensitivity of alkynol hydrogenation on shape-and size-controlled palladium nanocrystals: which sites are most active and selective?
M Crespo-Quesada, A Yarulin, M Jin… - Journal of the …, 2011 - ACS Publications
The activity and selectivity of structure-sensitive reactions are strongly correlated with the
shape and size of the nanocrystals present in a catalyst. This correlation can be exploited for …
shape and size of the nanocrystals present in a catalyst. This correlation can be exploited for …
The surface chemistry of metal-based hydrogenation catalysis
F Zaera - ACS Catalysis, 2017 - ACS Publications
The promotion of hydrogenation reactions by transition-metal-based heterogeneous
catalysts was established many decades ago but is still quite common in the chemical …
catalysts was established many decades ago but is still quite common in the chemical …
How to control the selectivity of palladium‐based catalysts in hydrogenation reactions: the role of subsurface chemistry
Discussed are the recent experimental and theoretical results on palladium‐based catalysts
for selective hydrogenation of alkynes obtained by a number of collaborating groups in a …
for selective hydrogenation of alkynes obtained by a number of collaborating groups in a …
Particle size effects in Pd-catalyzed electrooxidation of formic acid
Small carbon-supported Pd nanoparticles with controllable size (2.7− 9.0 nm) were
prepared by a solution chemistry method, characterized by transmission electron …
prepared by a solution chemistry method, characterized by transmission electron …
[HTML][HTML] Influence of particle size in Pd-catalysed selective hydrogenation of 1, 3-butadiene
OEB Corstius, JES van der Hoeven, GJ Sunley… - Journal of …, 2023 - Elsevier
Supported Pd nanoparticles are widely used as catalysts for the selective hydrogenation of
alkynes and diolefins. They have a high activity, but it remains challenging to limit over …
alkynes and diolefins. They have a high activity, but it remains challenging to limit over …
Morphology-dependent nanocatalysis: metal particles
Y Li, Q Liu, W Shen - Dalton transactions, 2011 - pubs.rsc.org
The rapid development of materials science now enables tailoring of metal and metal oxide
particles with tunable size and shape at the nanometre level. As a result, nanocatalysis is …
particles with tunable size and shape at the nanometre level. As a result, nanocatalysis is …