Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

Dual‐atom site catalysts (DACs) have emerged as a new frontier in heterogeneous catalysis
because the synergistic effect between adjacent metal atoms can promote their catalytic …

Separations relevant to trivalent actinides and lanthanides have been a focus of the f-
element community in the past few decades. A central focus of this effort has been …

We report the use of solution and solid-state 31P Nuclear Magnetic Resonance (NMR)
spectroscopy combined with Density Functional Theory calculations to benchmark the …

Electronic structure modulation among multiple metal sites is key to the design of efficient
catalysts. Most studies have focused on regulating 3d transition-metal active ions through …

Transition-metal oxides (TMOs) often struggle with challenges related to low electronic
conductivity and unsatisfactory cyclic stability toward cationic intercalation. In this work, we …

Determining the nature and extent of covalency of early actinide chemical bonding is a
fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and …

Synthetic strategies to yield molecular complexes of high-valent lanthanides, other than the
ubiquitous Ce4+ ion, are exceptionally rare, and thorough, detailed characterization in these …

Rare-earth and actinide complexes are critical for a wealth of clean-energy applications.
Three-dimensional (3D) structural generation and prediction for these organometallic …

Complexes of the form [U (η6-arene)(BH4) 3] where arene= C6H6; C6H5Me; C6H3-1, 3, 5-
R3 (R= Et, iPr, tBu, Ph); C6Me6; and triphenylene (C6H4) 3 were investigated towards an …