The reactions of frustrated Lewis pairs (FLPs) derived from B (C6F5) 3 and the bulky Lewis
bases 2, 2, 6, 6-tetramethylpiperidine (TMP), tri-tert-butylphosphine, and lutidine (Lut) with …

Thermodynamic data on complex formation between nitrogen donor ligands (amines,
pyridines) and group 11 monovalent ions in water and non-aqueous media are reviewed …

The acidities (p K a values) of proline amide derivatives are of great importance for
understanding the catalytic activity of proline-based organocatalysts. The development of …

We synthesized pyridylamine ligated arene-Ru (II) complexes and employed these
complexes for the catalytic acceptorless dehydrogenation of primary alcohols to carboxylic …

Samarium (II) iodide–water–amine reagents have emerged as some of the most powerful
reagents (E°=− 2.8 V) for the reduction of unactivated carboxylic acid derivatives to primary …

Amines and phosphines are widely utilized as bases and basic organocatalysts in organic
chemistry. Thus it is highly valuable to develop a coherent theoretical method that can …

We recently disclosed a new ruthenium‐catalyzed dehydrogenative cyclization process
(CDC) of diamine–monoboranes leading to cyclic diaminoboranes. In the present study, the …

The prediction of hydrogen-bond (H-bond) acceptor ability is crucial in drug design. This
important property is quantified in a large p K BHX database of consistently measured …

In this work, experimental hydrogen-bond (HB) enthalpies measured in previous works for a
wide range of acceptor molecules in dilute mixtures of 4-fluorophenol in non-polar solvents …

The kinetics of the SmI2/H2O/amine-mediated reduction of 1-chlorodecane has been
studied in detail. The rate of reaction is first order in amine and 1-chlorodecane, second …