A Stańczak, I Kipouros, P Eminger, EM Dunietz… - Coordination Chemistry …, 2025 - Elsevier
The broad class of O 2-activating coupled-binuclear copper (CBC) metalloenzymes contain a unique [Cu 2 O 2] catalytic core. This core is responsible for catalyzing challenging …
L Siebe, C Butenuth, A Stammler, H Bögge… - Inorganic …, 2024 - ACS Publications
Tetradentate-N4 ligands stabilize dinuclear {CuII (μ-1, 2-peroxo) CuII} and {CuIII (μ-O) 2CuIII} species, and CuII complexes of these ligands were reported to catalyze the oxidation …
J Heck, F Metz, S Buchenau, M Teubner… - Chemical …, 2022 - pubs.rsc.org
Copper guanidine quinolinyl complexes act as good entatic state models due to their distorted structures leading to a high similarity between Cu (I) and Cu (II) complexes. For a …
R Schneider, TA Engesser, C Näther… - Angewandte Chemie …, 2022 - Wiley Online Library
Abstract The CuI salts [Cu (CH3CN) 4] PF and [Cu (oDFB) 2] PF with the very weakly coordinating anion Al (OC (CF3) 3) 4−(PF) as well as [Cu (NEt3) 2] PF comprising the …
M Paul, M Teubner, B Grimm‐Lebsanft… - … A European Journal, 2020 - Wiley Online Library
The enzyme tyrosinase contains a reactive side‐on peroxo dicopper (II) center as catalytically active species in C− H oxygenation reactions. The tyrosinase activity of the …
We report the discovery that the molecule 1-(pyridin-2-ylmethylamino) propan-2-ol (HL) can reduce oxidative stress in neuronal C6 glioma cells exposed to reactive oxygen species (O2 …
J Moegling, A Hoffmann, F Thomas… - Angewandte Chemie …, 2018 - Wiley Online Library
Heteroscorpionate ligands of the bis (pyrazolyl) methane family have been applied in the stabilisation of terminal copper tosyl nitrenes. These species are highly active intermediates …
F Thomas, M Oster, F Schön, KC Göbgen… - Dalton …, 2021 - pubs.rsc.org
Copper nitrene complexes are highly reactive species and are known as intermediates in the copper catalyzed C–H amination. In this study, three novel copper tosyl nitrene …
The present study describes an original colorimetric method to visualize and quantify the local oxygen mass transfer around a rising bubble in reactive media. This method is based …