Analysis and control of acid sites in zeolites

A Palčić, V Valtchev - Applied Catalysis A: General, 2020 - Elsevier
The exceptional catalytic performance of zeolites is due to the presence of active sites in a
shape-selective environment, ie, in micropores with molecular dimensions. The present …

Heterogeneous iron-based catalysts for organic transformation reactions: a brief overview

MJ Baruah, R Dutta, MEA Zaki, KK Bania - Molecules, 2024 - pmc.ncbi.nlm.nih.gov
Iron (Fe) is considered to be one of the most significant elements due to its wide
applications. Recent years have witnessed a burgeoning interest in Fe catalysis as a …

Turning on Asymmetric Catalysis of Achiral Metal‐Organic Frameworks by Imparting Chiral Microenvironment

G Yang, W Shi, Y Qian, X Zheng, Z Meng… - Angewandte …, 2023 - Wiley Online Library
The development of heterogeneous asymmetric catalysts has attracted increasing interest in
synthetic chemistry but mostly relies on the immobilization of homogeneous chiral catalysts …

Counting Sites in Lewis Acid Zeolite Sn-Beta: Connecting Site Quantification Experiments and Spectroscopy To Investigate the Catalytic Activity for the Alcohol Ring …

L Ford, A Spanos, NA Brunelli - ACS Catalysis, 2023 - ACS Publications
Sn-Beta is a promising catalyst for numerous reactions involved in biomass upgrading and
fine chemical production, but it is complex with multiple types of active sites. The activity for …

Sulfonic acid-grafted hybrid porous polymer based on double-decker silsesquioxane as highly efficient acidic heterogeneous catalysts for the alcoholysis of styrene …

X Zhao, Q Wang, R Kunthom, H Liu - ACS Applied Materials & …, 2023 - ACS Publications
β-Alkoxyalcohols generated from epoxide ring-opening reactions are significant due to their
enormous value as pharmaceutical intermediates and fine chemicals. Using a phenyl …

Regioselective ring-opening of spiro-epoxyoxindoles by a dual-ligand zinc-based metal–organic framework as an efficient heterogeneous catalyst

P Patel, U Patel, B Parmar, A Dadhania… - ACS Applied Nano …, 2022 - ACS Publications
Developing a heterogeneous catalyst for alcoholysis/hydrolysis of spiro-epoxyoxindoles to
form β-alkoxy/β-hydroxy alcohols is an emerging and promising research area in the …

ADOR zeolite with 12× 8× 8-ring pores derived from IWR germanosilicate

Q Yue, V Kasneryk, M Mazur, S Abdi, Y Zhou… - Journal of Materials …, 2024 - pubs.rsc.org
Zeolites have been well known for decades as catalytic materials and adsorbents and are
traditionally prepared using the bottom-up synthesis method. Although it was productive for …

Understanding rates and regioselectivities for epoxide methanolysis within zeolites: mechanism and roles of covalent and non-covalent interactions

DS Potts, JK Komar, H Locht, DW Flaherty - ACS Catalysis, 2023 - ACS Publications
Rates and selectivities for liquid-phase reactions depend on the structure and acidity of
active sites within zeolite catalysts and the solvent environment surrounding the active sites …

Quantification of intraporous hydrophilic binding sites in Lewis acid zeolites and consequences for sugar isomerization catalysis

JC Vega-Vila, R Gounder - ACS Catalysis, 2020 - ACS Publications
Aqueous-phase sugar isomerization is catalyzed at lower turnover rates when Lewis acid
active sites are confined within high-defect zeolite micropores, because intraporous silanol …

Effect of exposed active sites of semi-amorphous Fe-BTC on photocatalytic CO2 cycloaddition reaction under ambient conditions

Y He, M Xu, J Xia, C Zhang, X Song, X Zhao, M Fu… - Molecular …, 2023 - Elsevier
The capture and efficient use of CO 2 is an important issue because CO 2 emissions by
burning fossil fuels is a primary cause of greenhouse effect. One of the best solutions to this …