The thermodynamic properties of the f-elements and their compounds. Part 2. The lanthanide and actinide oxides

RJM Konings, O Beneš, A Kovács, D Manara… - Journal of Physical …, 2014 - pubs.aip.org
A comprehensive review of the thermodynamic properties of the oxide compounds of the
lanthanide and actinide elements is presented. The available literature data for the solid …

Quantum chemical calculations and experimental investigations of molecular actinide oxides

A Kovacs, RJM Konings, JK Gibson, I Infante… - Chemical …, 2015 - ACS Publications
Actinides are the heaviest chemical elements with practical relevance. Among them, only
thorium and uranium can be found in nature in substantial quantities, while natural …

[图书][B] Comprehensive handbook of chemical bond energies

YR Luo - 2007 - taylorfrancis.com
Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …

Recent advances in computational actinoid chemistry

D Wang, WF van Gunsteren, Z Chai - Chemical Society Reviews, 2012 - pubs.rsc.org
We briefly review advances in computational actinoid (An) chemistry during the past ten
years in regard to two issues: the geometrical and electronic structures, and reactions. The …

Oxidation studies of dipositive actinide ions, An2+ (An= Th, U, Np, Pu, Am) in the gas phase: Synthesis and characterization of the isolated uranyl, neptunyl, and …

JK Gibson, RG Haire, M Santos, J Marçalo… - The Journal of …, 2005 - ACS Publications
Reactions of atomic and ligated dipositive actinide ions, An2+, AnO2+, AnOH2+, and
AnO22+ (An= Th, U, Np, Pu, Am) were systematically studied by Fourier transform ion …

Gas-phase energetics of actinide oxides: an assessment of neutral and cationic monoxides and dioxides from thorium to curium

J Marcalo, JK Gibson - The Journal of Physical Chemistry A, 2009 - ACS Publications
An assessment of the gas-phase energetics of neutral and singly and doubly charged
cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium …

Radionuclide analysis using collision–reaction cell ICP-MS technology: a review

S Diez-Fernández, H Isnard, A Nonell… - Journal of Analytical …, 2020 - pubs.rsc.org
The analysis of radionuclides (RN) is of major concern in different fields like the
environment, geosciences, the nuclear industry, and medical research. Inductively coupled …

Ionization energies for the actinide mono-and dioxides series, from Th to Cm: theory versus experiment

I Infante, A Kovacs, GL Macchia… - The Journal of …, 2010 - ACS Publications
The results of a computational study with multiconfigurational quantum chemical methods on
actinide monoxides (AnO) and dioxides (AnO2) for An= Th, Pa, U, Np, Pu, Am, and Cm, are …

f-Block reactions of metal cations with carbon dioxide studied by inductively coupled plasma tandem mass spectrometry

RM Cox, KM Melby, AD French… - Physical Chemistry …, 2024 - pubs.rsc.org
f-Block chemistry offers an opportunity to test current knowledge of chemical reactivity. The
energy dependence of lanthanide cation (Ln+= Ce+, Pr+, Nd+–Eu+) and actinide cation …

[HTML][HTML] Bond energies of ThO+ and ThC+: A guided ion beam and quantum chemical investigation of the reactions of thorium cation with O2 and CO

RM Cox, M Citir, PB Armentrout, SR Battey… - The Journal of …, 2016 - pubs.aip.org
Kinetic energy dependent reactions of Th+ with O 2 and CO are studied using a guided ion
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with O 2 is …