The quest for single component molecular metals within neutral transition metal complexes

MFG Velho, RAL Silva, D Belo - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Twenty years ago, the molecular materials community accomplished a major breakthrough
with the report of the first single component molecular metal (SCMM). Previously it was …

Metalloligand Nickel Bis (Dithiolene) Based Metal–Organic Frameworks for Efficient Photocurrent and Photothermal Conversion

Z Zhang, N Xu, Y Zhou, ND Shepherd… - ACS Materials …, 2024 - ACS Publications
Nickel bis (dithiolene) complexes are strong sunlight absorbers with high thermal-and
photostability and are nonluminescent, resulting in remarkable photothermal properties …

1, 2-Diselenolene ligands and related metal complexes: Design, synthesis and applications

A Pintus, M Arca - Coordination Chemistry Reviews, 2022 - Elsevier
Diselenolene metal complexes show a variety of chemical and physical properties, such as
redox activity, visible–near-infrared absorption, optical nonlinearity, conductivity, and …

Diradical character of neutral heteroleptic bis (1, 2-dithiolene) metal complexes: Case study of [Pd (Me2timdt)(mnt)](Me2timdt= 1, 3-dimethyl-2, 4, 5 …

MC Aragoni, C Caltagirone, V Lippolis… - Inorganic …, 2020 - ACS Publications
The reaction of the bis (1, 2-dithiolene) complex [Pd (Me2timdt) 2](1; Me2timdt•–=
monoreduced 1, 3-dimethyl-2, 4, 5-trithioxoimidazolidine) with Br2 yielded the complex [Pd …

Near-infrared absorption properties of neutral bis (1, 2-dithiolene) platinum (II) complexes using density functional theory

XH Luong, NNT Pham, KL An, SU Lee, SS Kim… - Nanomaterials, 2022 - mdpi.com
Small metal complexes are highly interesting for bioimaging because of their excellent near-
infrared (NIR) absorption properties. In this study, neutral complexes of platinum (II) …

Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt (bipy)(Naph-edt)](bipy= 2, 2 …

MC Aragoni, M Arca, M Binda, C Caltagirone… - Dalton …, 2021 - pubs.rsc.org
The photoconducting properties of platinum diimine-dithiolate complex [Pt (bipy)(Naph-
edt)](1; bipy= 2, 2′-bipyridine; Naph-edt2−= 2-naphthylethylene-1, 2-dithiolate) were …

Organic photodetectors

V Pecunia, D Natali, M Caironi - Photodetectors, 2023 - Elsevier
Organic photodetectors represent an emerging field of organic electronics. The peculiarities
of organic semiconductors make them attractive for various, innovative and disruptive …

Synthesis, electrical conductivity and NIR absorption of some metal dithiolene complexes: some recent developments

R Ghosh - Indian Journal of Chemistry (IJC), 2023 - op.niscpr.res.in
Square planar transition metal bis (dithiolene) complexes are of upsurge interest throughout
the last few decades due to its varied interesting physical as well as physicochemical …

Can serendipity still hold any surprises in the coordination chemistry of mixed-donor macrocyclic ligands? The case study of pyridine-containing 12-membered …

A Garau, G Picci, M Arca, AJ Blake, C Caltagirone… - Molecules, 2021 - mdpi.com
This study investigates the coordination chemistry of the tetradentate pyridine-containing 12-
membered macrocycles L1-L3 towards Platinum Group metal ions PdII, PtII, and RhIII. The …