3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Transition-metal-catalyzed cross-couplings through carbene migratory insertion

Y Xia, D Qiu, J Wang - Chemical reviews, 2017 - ACS Publications
Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

Cobalt-catalyzed C–H activation

M Moselage, J Li, L Ackermann - ACS Catalysis, 2016 - ACS Publications
Catalytic C–H activation has emerged as a powerful tool for sustainable syntheses. In the
recent years, notable success was achieved with the development of cobalt-catalyzed C–H …

(Pentamethylcyclopentadienyl) cobalt (III)‐Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity

T Yoshino, S Matsunaga - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Abstract High‐valent (pentamethylcyclopentadienyl) cobalt (III)[Cp* Co (III)] catalysts were
found as inexpensive alternatives to (pentamethylcyclopentadienyl) rhodium (III)[Cp* Rh (III)] …

Recent advances in chelation-assisted site-and stereoselective alkenyl C–H functionalization

J Zhang, X Lu, C Shen, L Xu, L Ding… - Chemical Society …, 2021 - pubs.rsc.org
Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

Transition‐Metal‐Catalyzed Denitrogenative Annulation to Access High‐Valued N‐Heterocycles

SK Das, S Roy, B Chattopadhyay - … Chemie International Edition, 2023 - Wiley Online Library
Over the past few years, the development of efficient methods to construct high‐valued N‐
heterocyclic molecules have received massive attention owing to their extensive application …

Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal‐Catalyzed Cascade C–H Activation/Carbene Insertion …

Y Xiang, C Wang, Q Ding… - Advanced Synthesis & …, 2019 - Wiley Online Library
This review covers some unique diazo compounds, the coupling partners to access various
versatile functionalized nitrogen heterocycles, such as indoles, indolines, isoquinolines …

Cross‐Coupling of α‐Carbonyl Sulfoxonium Ylides with C− H Bonds

M Barday, C Janot, NR Halcovitch, J Muir… - Angewandte …, 2017 - Wiley Online Library
The functionalization of carbon–hydrogen bonds in non‐nucleophilic substrates using α‐
carbonyl sulfoxonium ylides has not been so far investigated, despite the potential safety …

Cycloaddition reactions of enoldiazo compounds

QQ Cheng, Y Deng, M Lankelma… - Chemical Society Reviews, 2017 - pubs.rsc.org
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …