Triptycenes are an intriguing class of organic molecules with several unusual
characteristics, such as a propeller‐like shape, saddle‐like cavities around a symmetrical …

Over the years, hydrosilylation of terminal alkenes has emerged as one of the most
prominent applications of homogeneous catalysis. While most of the relevant reports …

Here we report an efficient synthesis of optically active ladder-type molecules and polymers
through intramolecular cyclization of chiral triptycenes containing bis [2-(4-alkoxyphenyl) …

Iptycene is a class of 3D, rigid, and arene‐rich frameworks and has been incorporated into
photoactive π‐systems for a variety of purposes, including tuning interchromophore …

A series of chiral fluorescent polymers containing optically active triptycene units in the main
chain were synthesized via Sonogashira–Hagihara coupling copolymerizations of (R, R)-or …

Triptycene derivatives are used extensively in supramolecular and materials chemistry,
however, most are prepared using a multi-step synthesis involving the generation of a …

Background: The Hirao reaction discovered ca. 35 years ago is an important P–C coupling
protocol between dialkyl phosphites and aryl halides in the presence of Pd (PPh3) 4 as the …

This chapter covers the literature published during 2017 relating to the synthesis, the
reactivity and the application of phosphines, excluding the chemistry of their metal …

We report on the design and synthesis of triptycene–peptide hybrids (TPHs), 5, syn-6, and
anti-6, which are conjugates of a triptycene core unit with two or three cationic KKKGG …

A pair of optically pure triptycene derivatives ((R, R)-and (S, S)-3) containing fluorescent
pyrene-based π-conjugated pendant groups attached through amide spacers were …