Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Bowls, hoops, and saddles: synthetic approaches to curved aromatic molecules

MA Majewski, M Stępień - Angewandte Chemie International …, 2019 - Wiley Online Library
This review summarizes recent advances in the chemistry of curved aromatic molecules. By
focusing on the key accomplishments of the last decade, we provide a general overview of …

Synthesis and functionalization of porphyrins through organometallic methodologies

S Hiroto, Y Miyake, H Shinokubo - Chemical reviews, 2017 - ACS Publications
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

From macrocycles to quantum rings: Does aromaticity have a size limit?

M Jirásek, HL Anderson, MD Peeks - Accounts of Chemical …, 2021 - ACS Publications
Conspectus The ring currents of aromatic and antiaromatic molecules are remarkable
emergent phenomena. A ring current is a quantum-mechanical feature of the whole system …

Template-directed synthesis of molecular nanorings and cages

PS Bols, HL Anderson - Accounts of chemical research, 2018 - ACS Publications
Conspectus This Account is about templates as construction tools: molecules for making
molecules. A template organizes the reactants and provides information to promote …

Aromatic and antiaromatic ring currents in a molecular nanoring

MD Peeks, TDW Claridge, HL Anderson - Nature, 2017 - nature.com
Aromatic and antiaromatic molecules—which have delocalized circuits of [4 n+ 2] or [4 n]
electrons, respectively—exhibit ring currents around their perimeters,,,. The direction of the …

The entangled triplet pair state in acene and heteroacene materials

CK Yong, AJ Musser, SL Bayliss, S Lukman… - Nature …, 2017 - nature.com
Entanglement of states is one of the most surprising and counter-intuitive consequences of
quantum mechanics, with potent applications in cryptography and computing. In organic …

Increasing the size and complexity of discrete 2D metallosupramolecules

H Wang, Y Li, N Li, A Filosa, X Li - Nature Reviews Materials, 2021 - nature.com
Owing to the reversible, directional and predictable nature of metal–ligand coordination,
coordination-driven self-assembly has emerged as a powerful bottom-up strategy for …

Porphyrinoids, a unique platform for exploring excited-state aromaticity

J Kim, J Oh, A Osuka, D Kim - Chemical Society Reviews, 2022 - pubs.rsc.org
Recently, Baird (anti) aromaticity has been referred to as a description of excited-state (anti)
aromaticity. With the term of Baird's rule, recent studies have intensively verified that the …

Triplet-pair states in organic semiconductors

AJ Musser, J Clark - Annual review of physical chemistry, 2019 - annualreviews.org
Entanglement of states is one of the most surprising and counterintuitive consequences of
quantum mechanics, with potent applications in cryptography and computing. In organic …