Basic terminology of stereochemistry (IUPAC Recommendations 1996)

GP Moss - Pure and applied chemistry, 1996 - degruyter.com
Many of the symbols used in stereochemical nomenclature are mentioned but details of their
assignment or their incorporation into chemical names are left to the appropriate …

Anticorrosive properties of green-synthetized benzylidene derivatives for mild steel in hydrochloric acid: An experimental study combined with DFTB and molecular …

CM Fernandes, L Guedes, LX Alvarez… - Journal of Molecular …, 2022 - Elsevier
Two benzylidene derivatives anisaldehyde-cyanoguanidine imine (CMBG) and p–
dimethylaminobenzaldehyde-TRIS imine (DBHP) were prepared according to the 12 …

Recent Developments in the Ring‐Chain Tautomerism of 1, 3‐Heterocycles

L Lázár, F Fülöp - European Journal of Organic Chemistry, 2003 - Wiley Online Library
Some important results from the past seven years on the ring‐chain tautomerism of 1, 3‐
heterocycles are reviewed, including substituent effects on the tautomeric equilibria and …

Novel immunomodulator FTY720 is phosphorylated in rats and humans to form a single stereoisomer. Identification, chemical proof, and biological characterization of …

R Albert, K Hinterding, V Brinkmann… - Journal of medicinal …, 2005 - ACS Publications
In vivo phosphorylation of FTY720 (1) in rats and humans resulted exclusively in the
biologically active (S)-configured enantiomer, which was proven by an ex vivo o …

Environmentally friendly and regioselective one-pot synthesis of imines and oxazolidines serinol derivatives and their use for rubber cross-linking

V Barbera, G Leonardi, AM Valerio… - ACS Sustainable …, 2020 - ACS Publications
High-yield regioselective synthesis of imines and oxazolidines derivatives of 2-amino-1, 3-
propandiol (serinol) was achieved by performing the reaction with aldehydes and ketones …

A True Reverse Anomeric Effect Does Exist After All: A Hydrogen Bonding Stereocontrolling Effect in 2-Iminoaldoses

E Matamoros, EMS Pérez, ME Light… - The Journal of …, 2024 - ACS Publications
The reverse anomeric effect is usually associated with the equatorial preference of nitrogen
substituents at the anomeric center. Once postulated as another anomeric effect with …

NMR studies of hydroxy Schiff bases

PE Hansen, Z Rozwadowski… - Current Organic …, 2009 - ingentaconnect.com
The review covers the use of chemical shifts, isotope effects on chemical shifts and coupling
constants in the description of Schiff bases. o-Hydroxy Schiff bases are often tautomeric and …

Preparation and analysis of oligonucleotides containing lesions resulting from C5 '-oxidation

T Kodama, MM Greenberg - The Journal of organic chemistry, 2005 - ACS Publications
Hydrogen atom abstraction from the C5 '-position of nucleotides in DNA results in direct
strand scission. The newly formed 5 '-termini of the cleaved DNA consists of alkali-labile …

[HTML][HTML] Exploring and Re-Assessing Reverse Anomeric Effect in 2-Iminoaldoses Derived from Mono-and Polynuclear Aromatic Aldehydes

EMS Pérez, E Matamoros, P Cintas, JC Palacios - Molecules, 2024 - mdpi.com
A curious and noticeable structural feature in Schiff bases from 2-aminoaldoses is the fact
that imino tautomers arranged equatorially in the most stable ring conformation exhibit a …

Schiff Bases and Stereocontrolled Formation of Fused 1, 3-Oxazolidines from 1-Amino-2-Indanol: A Systematic Study on Structure and Mechanism

E Matamoros, ME Light, P Cintas, JC Palacios - Molecules, 2023 - mdpi.com
This paper thoroughly explores the formation of Schiff bases derived from salicylaldehydes
and a conformationally restricted amino alcohol (1-amino-2-indanol), as well as the …