Strategies to achieve spatiotemporal regulation of pre‐existing alkenes via external stimuli
are essential given the ubiquity of feedstock olefins in chemistry and their downstream …

This review outlines the most noteworthy achievements of the last few years in the renascent
field of positional and geometrical isomerization of alkenes using iron catalysis, from a …

Simultaneous sulfonylation/arylation of styrene derivatives is achieved in a photoredox‐
catalyzed three‐component reaction using visible light. A broad variety of difunctionalized …

Transition-metal-catalyzed decarbonylation reactions of aliphatic carboxylic acids produce
olefins via one carbon degradation. Recently, tremendous progress has been made in the …

A homogeneous Pd‐catalyzed stereodivergent reduction of alkynes to Z and E alkenes by
using H2O as the H2 source is presented. Mediated by a diboron reagent, the transfer …

We report a method for palladium-catalysed chain-running isomerization of terminal and
internal alkenes. Using an air-stable 2, 9-dimethylphenanthroline-palladium catalyst in …

A palladium (II)-catalyzed hydroboration of aryl alkenes with stable and easy-to-handle
(pinacolato) diboron (B2pin2) under mild conditions has been developed. Acetic acid acted …

Strategien zur raumzeitlichen Steuerung von Alkenen durch einen äußeren Reiz sind
angesichts der Allgegenwart von Rohstoff‐Olefinen in der Chemie und ihren …

An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described.
A wide variety of trans-2-olefins bearing various functional groups can be obtained with high …

In contrast to the kinetically favored outward isomerization‐hydrocarbonylation of alkenes,
the disfavored inward isomerization‐hydrocarbonylation of alkenes remains an important …