This review is the counterpart of a 2018 Chemical Reviews article (Adero, PO; Amarasekara,
H.; Wen, P.; Bohé, L.; Crich, D. Chem. Rev. 2018, 118, 8242–8284) that examined the …

Methodology toward the stereoselective 1, 2-cis glycoside linkage using intramolecular
aglycon delivery (IAD) has been extensively developed. In the last two decades, progress …

β-Stereoselective mannosylations were conducted using a 1, 2-anhydromannose donor and
mono-ol acceptors in the presence of a glycosyl-acceptor-derived borinic ester. Reactions …

A goal for an HIV-1 vaccine is to overcome virus variability by inducing broadly neutralizing
antibodies (bnAbs). One key target of bnAbs is the glycan-polypeptide at the base of the …

This Perspective outlines work in the Crich group on the diastereoselective synthesis of the
so-called difficult classes of glycosidic bond: the 2-deoxy-β-glycopyranosides, the β …

The main advances in the chemistry of acetylene in superbasic media achieved over the last
five years are analyzed. Particular emphasis is placed on the ethynylation of aldehydes and …

A Minireview with 51 references covering the two-step tethering and intramolecular
glycosylation process termed intramolecular aglycon delivery (IAD). Specifically …

A new and efficient approach for direct and stereoselective synthesis of β‐
mannopyranosides by anomeric O‐alkylation has been developed. This anomeric O …

N-Glycan oxazolines have found widespread use as activated donor substrates for endo-β-
N-acetylglucosaminidase (ENGase) enzymes, an important application that has …

A methodology directed towards the stereoselective construction of 1, 2‐cis‐glycosides
through naphthylmethyl (NAP) ether mediated intramolecular aglycon derivery (IAD) has …