Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Small molecule activation by well-defined compounds of heavy p-block elements
K Oberdorf, C Lichtenberg - Chemical Communications, 2023 - pubs.rsc.org
The creative design and exploration of new bonding motifs and molecular architectures in
main group chemistry have pushed the boundaries of reactivity in this field of research. In …
main group chemistry have pushed the boundaries of reactivity in this field of research. In …
Sn (ii)–carbon bond reactivity: radical generation and consumption via reactions of a stannylene with alkynes
Thermal Sn–C cleavage in the diarylstannylene Sn (AriPr4) 2 (AriPr4= C6H3-2, 6-(C6H3-2,
6-iPr2) 2) was used to generate˙ Sn (AriPr4) and˙ AriPr4 radicals for alkyne arylstannylation …
6-iPr2) 2) was used to generate˙ Sn (AriPr4) and˙ AriPr4 radicals for alkyne arylstannylation …
Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me3P)2(Ph3P)Rh≡E‐Ar*] (E=Sn, Pb)
M Widemann, K Eichele, H Schubert… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Tetrylidynes [(Me3P) 2 (Ph3P) Rh≡ SnAr*](10) and [(Me3P) 2 (Ph3P) Rh≡
PbAr*](11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3P) …
PbAr*](11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3P) …
A neutral germanium/phosphorus frustrated Lewis pair and its contrasting reactivity compared to its silicon analogue
TA Kinder, R Pior, S Blomeyer… - … A European Journal, 2019 - Wiley Online Library
Abstract Chlorogermane (C2F5) 3GeCl with very electronegative pentafluoroethyl groups
was converted with LiCH2P (tBu) 2 to obtain the intramolecular frustrated Lewis pair …
was converted with LiCH2P (tBu) 2 to obtain the intramolecular frustrated Lewis pair …
Solvent‐Dependent Oxidative Addition and Reductive Elimination of H2 Across a Gallium‐Zinc Bond
LJ Morris, T Rajeshkumar, A Okumura… - Angewandte Chemie …, 2022 - Wiley Online Library
H2 adds reversibly across the metal‐metal bond of [(BDI) Ga (H)− Zn (tmeda)(thf)][BAr4F](
BDI=[HC {C (CH3) N (2, 6‐iPr2‐C6H3)} 2]−, TMEDA= N, N, N′, N …
BDI=[HC {C (CH3) N (2, 6‐iPr2‐C6H3)} 2]−, TMEDA= N, N, N′, N …
Controlling Oxidative Addition and Reductive Elimination at Tin (I) via Hemi‐Lability
We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant
amine donors that is capable of reversibly activating E‐H bonds at one or both of the tin …
amine donors that is capable of reversibly activating E‐H bonds at one or both of the tin …
Exploring the Reactivity of a Frustrated Sn/P Lewis Pair: The Highly Selective Complexation of the cis‐Azobenzene Photoisomer
P Holtkamp, D Poier, B Neumann… - … A European Journal, 2021 - Wiley Online Library
The reactivity of the geminal frustrated Lewis pair (FLP)(F5C2) 3SnCH2P (tBu) 2 (1) was
explored by reacting it with a variety of small molecules (PhOCN, PhNCS, PhCCH, tBuCCH …
explored by reacting it with a variety of small molecules (PhOCN, PhNCS, PhCCH, tBuCCH …
Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects
EN Nikolaevskaya, MA Syroeshkin… - Mendeleev …, 2023 - Elsevier
A general aspect of synthesis, modern trends and application prospects of organic
derivatives of group 14 elements are briefly overviewed. This survey concerns actual …
derivatives of group 14 elements are briefly overviewed. This survey concerns actual …
Halogen Bonds of Halotetrafluoropyridines in Crystals and Co‐crystals with Benzene and Pyridine
J Schwabedissen, PC Trapp… - … A European Journal, 2019 - Wiley Online Library
The structures of the three para‐substituted halotetrafluoropyridines with chlorine, bromine,
and iodine have been determined in the solid state (X‐ray diffraction). The structures of …
and iodine have been determined in the solid state (X‐ray diffraction). The structures of …