γ‐Ray Driven Aqueous‐Phase Methane Conversions into Complex Molecules up to Glycine

F Fang, X Sun, Y Liu, Z Jiang, M Wang… - Angewandte …, 2024 - Wiley Online Library
Fundamental understanding of initial evolutions of molecules in the universe is of great
interest and importance. CH4 is one of the abundant simple molecules in the universe …

Ozone production in electron irradiated CO 2: O 2 ices

DV Mifsud, Z Kaňuchová, S Ioppolo… - Physical Chemistry …, 2022 - pubs.rsc.org
The detection of ozone (O3) in the surface ices of Ganymede, Jupiter's largest moon, and of
the Saturnian moons Rhea and Dione, has motivated several studies on the route of …

Chemical reactions in H2O:CO interstellar ice analogues promoted by energetic heavy-ion irradiation

ALF De Barros, C Mejía… - Monthly Notices of …, 2022 - academic.oup.com
ABSTRACT H2O: CO, at concentrations of (3: 2) and (10: 1), was condensed on CsI
substrate at 15 K and irradiated with 46-MeV 58Ni11+ ion beam. Radiolysis induced by fast …

Oxygen isotope equilibria of O-bearing organic compounds based on first principle quantum mechanical models, and implications for their use in the study of …

S Bhattacharjee, JM Eiler - Geochimica et Cosmochimica Acta, 2024 - Elsevier
We report theoretically calculated equilibrium oxygen isotopic fractionation factors (17 O/16
O, 18 O/16 O) between a set of representative O-bearing organic molecules and water, as …

Swift heavy ions irradiation of water ice at different temperatures: hydrogen peroxide and ozone synthesis and sputtering yield

C Mejía, ALF De Barros, H Rothard… - Monthly Notices of …, 2022 - academic.oup.com
Water ices at 15 and 144 K were bombarded by swift heavy ions, 45.8 MeV 58Ni11+ and
606 MeV 64Zn26+, to measure the induced chemical and physical effects. The column …

Heavy ion radiolysis of the chiral terpene α-pinene

ALF de Barros, A Ricca, A Bychkova… - Monthly Notices of …, 2024 - academic.oup.com
Radiolysis of α-pinene by 61.3 MeV 84Kr15+ ions was analysed with the scope to simulate
the effects of heavy ion cosmic ray bombardment on chiral molecules in the interstellar …

Modifications of astrophysical ices induced by cosmic rays-I. Water, carbon monoxide, and methanol mixtures

C Mejía, ALF de Barros, A Domaracka… - Astronomy & …, 2024 - aanda.org
Aims. Astrophysical ices on dust grain mantles in the interstellar medium (ISM) and dense
circumstellar envelopes (CSEs) are continuously exposed to galactic cosmic rays (GCRs). In …

Radiolysis of NH3:CO ice mixtures – implications for Solar system and interstellar ices

ALF De Barros, A Bergantini… - Monthly Notices of …, 2020 - academic.oup.com
Experimental results on the processing of NH3: CO ice mixtures of astrophysical relevance
by energetic (538 MeV 64Ni24+) projectiles are presented. NH3 and CO are two molecules …

Proton and Electron Irradiations of CH4:H2O Mixed Ices

DV Mifsud, P Herczku, B Sulik, Z Juhász, I Vajda… - Atoms, 2023 - mdpi.com
The organic chemistry occurring in interstellar environments may lead to the production of
complex molecules that are relevant to the emergence of life. Therefore, in order to …

Decomposition of the CO stretching vibration band of laboratory H2O–CO ices irradiated by heavy ions

E Seperuelo Duarte, ALF de Barros… - Monthly Notices of …, 2021 - academic.oup.com
ABSTRACT H2O and CO molecules are the main constituents of the interstellar dust grain
ice mantles. Infrared spectra of the ices in line of sights of young stellar objects and …