Vinyl epoxides in organic synthesis

J He, J Ling, P Chiu - Chemical Reviews, 2014 - ACS Publications
Vinyl epoxides are molecules with a rich chemistry because of the strained oxirane, already
a reactive moiety on its own, in proximity with a carbon− carbon double bond. The chemistry …

Cutting-edge and time-honored strategies for stereoselective construction of C–N bonds in total synthesis

AK Mailyan, JA Eickhoff, AS Minakova, Z Gu… - Chemical …, 2016 - ACS Publications
The main objective of this review is to provide a comprehensive survey of methods used for
stereoselective construction of carbon–nitrogen bonds during the total synthesis of nitrogen …

Linking traumatic brain injury to chronic traumatic encephalopathy: identification of potential mechanisms leading to neurofibrillary tangle development

BP Lucke-Wold, RC Turner, AF Logsdon… - Journal of …, 2014 - liebertpub.com
Significant attention has recently been drawn to the potential link between head trauma and
the development of neurodegenerative disease, namely chronic traumatic encephalopathy …

Recent applications and developments of organic azides in total synthesis of natural products

H Tanimoto, K Kakiuchi - Natural product communications, 2013 - journals.sagepub.com
Organic azides have been exploited since their discovery because of their high reactivities.
Various organic reactions using azides have been synthetically applied in chemical biology …

Selective deprotection of silyl ethers

RD Crouch - Tetrahedron, 2013 - Elsevier
Reactions, which permit the selective deprotection of one silyl-protected alcohol in the
presence of another are reviewed. This review covers examples reported in the literature …

Allylic azides: synthesis, reactivity, and the Winstein rearrangement

AS Carlson, JJ Topczewski - Organic & biomolecular chemistry, 2019 - pubs.rsc.org
Organic azides are useful synthetic intermediates, which demonstrate broad reactivity.
Unlike most organic azides, allylic azides can spontaneously rearrange to form a mixture of …

Recent advances in stoichiometric phosphine-mediated organic synthetic reactions

S Xu, Z He - RSC advances, 2013 - pubs.rsc.org
Organic synthetic reactions mediated by tertiary phosphines have attracted much attention in
the organic chemistry community in the past two decades. These reactions can be divided …

Spot the difference in reactivity: a comprehensive review of site-selective multicomponent conjugation exploiting multi-azide compounds

H Tanimoto, T Tomohiro - Chemical Communications, 2024 - pubs.rsc.org
Going beyond the conventional approach of pairwise conjugation between two molecules,
the integration of multiple components onto a central scaffold molecule is essential for the …

Preparation of a stable bicyclic aziridinium ion and its ring expansion toward piperidines and azepanes

J Choi, NN Yadav, HJ Ha - Asian Journal of Organic Chemistry, 2017 - Wiley Online Library
The formation of the stable form of 1‐azabicyclo [4.1. 0] heptane tosylate was successfully
achieved from 2‐[4‐tolenesulfonyloxybutyl] aziridine, by stirring in MeCN at room …

Advances in C—N3 Retention Reactions Involving Organic Azides

W Fang, Y Xin, X Qiang - Chinese Journal of Organic Chemistry, 2023 - sioc-journal.cn
Organic azides are widely used in the total synthesis of natural products, medicinal
chemistry and material chemistry. Azides tend to release molecular nitrogen to construct …