Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Single-molecule nano-optoelectronics: insights from physics

P Li, L Zhou, C Zhao, H Ju, Q Gao, W Si… - Reports on Progress …, 2022 - iopscience.iop.org
Single-molecule optoelectronic devices promise a potential solution for miniaturization and
functionalization of silicon-based microelectronic circuits in the future. For decades of its fast …

Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets

CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

Studies of hysteresis and quantum tunnelling of the magnetisation in dysprosium (III) single molecule magnets

F Ortu, D Reta, YS Ding, CAP Goodwin… - Dalton …, 2019 - pubs.rsc.org
We report magnetic hysteresis studies of three Dy (III) single-molecule magnets (SMMs). The
three compounds are [Dy (tBuO) Cl (THF) 5][BPh4](1),[K (18-crown-6-ether)(THF) 2][Dy …

Exploring the role of intramolecular interactions in the suppression of quantum tunneling of the magnetization in a 3d-4f single-molecule magnet

MN Akhtar, MA AlDamen, CD McMillen… - Inorganic …, 2021 - ACS Publications
Hydroxide-bridged FeIII4LnIII2 clusters having the general formula [Fe4Ln2 (μ3-OH) 2
(mdea) 6 (SCN) 2 (NO3) 2 (H2O) 2]· 4H2O· 2MeCN {Ln= Y (1), Dy (2), mdea= N …

Closely Related Organometallic Er (III) Single-Molecule Magnets with Sizably Different Relaxation Times of Quantum Tunneling of Magnetization

T Xue, YS Ding, D Reta, QW Chen, X Zhu… - Crystal Growth & …, 2022 - ACS Publications
Single-molecule magnets (SMMs) are of interest for storage and quantum processing of
information. Herein, we report three new SMMs,([K (DME) 2][Er (COTTBS2) 2](1),[K (18-C …

Hilbert Space in Isotopologue Dy(III) SMM Dimers: Dipole Interaction Limit in [163/164Dy2(tmhd)6(tape)]0 Complexes

TT Ruan, E Moreno-Pineda, M Schulze… - Inorganic …, 2023 - ACS Publications
Single-molecule magnets are molecular complexes proposed to be useful for information
storage and quantum information processing applications. In the quest for multilevel systems …

Vibronic effects on the quantum tunnelling of magnetisation in Kramers single-molecule magnets

A Mattioni, JK Staab, WJA Blackmore, D Reta… - Nature …, 2024 - nature.com
Single-molecule magnets are among the most promising platforms for achieving molecular-
scale data storage and processing. Their magnetisation dynamics are determined by the …

Colossal zero-field-cooled exchange bias via tuning compensated ferrimagnetic in kagome metals

H Zhou, Y Cao, S Khmelevskyi, Q Zhang… - Journal of the …, 2024 - ACS Publications
Exchange bias (EB) is a crucial property with widespread applications but particularly occurs
by complex interfacial magnetic interactions after field cooling. To date, intrinsic zero-field …

Windmill-like Ln4 Clusters [Ln = Tb(III) and Dy(III)] Bridged by [α-AsW9O33]9– Unit Showing Zero-Field SMM Behavior: Experimental and Theoretical Investigation

S Kapurwan, A Mondal, PK Sahu, S Konar - Inorganic Chemistry, 2022 - ACS Publications
Herein, two polyoxometalate (POM)-ligated tetranuclear rare-earth metal complexes having
the molecular formula [Cs x K24–x {Ln4 (H2O) 8 (α-AsW9O33) 4}]· y H2O {x= 5, y= 20, and …