Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

Telechelic polymers by living and controlled/living polymerization methods

MA Tasdelen, MU Kahveci, Y Yagci - Progress in Polymer Science, 2011 - Elsevier
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are
used as cross-linkers, chain extenders, and important building blocks for various …

Mass spectrometry in polymer chemistry: a state-of-the-art up-date

T Gruendling, S Weidner, J Falkenhagen… - Polymer …, 2010 - pubs.rsc.org
Two decades after the introduction of matrix assisted laser desorption/ionization (MALDI)
and electrospray ionization (ESI), soft ionization mass spectrometry represents a powerful …

Kinetic subtleties of nitroxide mediated polymerization

D Bertin, D Gigmes, SRA Marque… - Chemical Society Reviews, 2011 - pubs.rsc.org
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …

Lectin recognizable biomaterials synthesized via nitroxide-mediated polymerization of a methacryloyl galactose monomer

SRS Ting, EH Min, P Escale, M Save, L Billon… - …, 2009 - ACS Publications
The preparation of poly (2-(2′, 3′, 4′, 6′-tetra-O-acetyl-β-d-galactosyloxy) ethyl
methacrylate-co-styrene)(P (AcGalEMA-co-S)) glycopolymer was performed via nitroxide …

Scavenging of organic C-centered radicals by nitroxides

EG Bagryanskaya, SRA Marque - Chemical reviews, 2014 - ACS Publications
1. INTRODUCTION For more than two decades, from the 1960s to the mid-1980s,
fundamental research in radical chemistry aroused tremedeous interest in the physical …

A minimal amount of acrylonitrile turns the nitroxide‐mediated polymerization of methyl methacrylate into an almost ideal controlled/living system

J Nicolas, S Brusseau… - Journal of Polymer Science …, 2010 - Wiley Online Library
Nitroxide‐mediated controlled/living free‐radical polymerization of methyl methacrylate
initiated by the SG1‐based alkoxyamine BlocBuilder was successfully performed in bulk at …

Glass transition breadths and composition profiles of weakly, moderately, and strongly segregating gradient copolymers: Experimental results and calculations from …

MM Mok, J Kim, CLH Wong, SR Marrou, DJ Woo… - …, 2009 - ACS Publications
Gradient copolymers are prepared from comonomer systems with a range of segregation
strengths and homopolymer glass transition temperature (T g) differences to explore the …