Role of external field in polymerization: mechanism and kinetics

YN Zhou, JJ Li, YY Wu, ZH Luo - Chemical reviews, 2020 - ACS Publications
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

Switchable polymerization catalysts

AJ Teator, DN Lastovickova, CW Bielawski - Chemical reviews, 2016 - ACS Publications
The intrinsic physical properties and functionalities displayed by synthetic polymers are
directly correlated to their respective microstructures. For example, complex biopolymers …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

Light-activated olefin metathesis: catalyst development, synthesis, and applications

O Eivgi, RS Phatake, NB Nechmad… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus The most important means for tuning and improving a catalyst's properties is the
delicate exchange of the ligand shell around the central metal atom. Perhaps for no other …

Removing ruthenium residues from olefin metathesis reaction products

GC Vougioukalakis - Chemistry–A European Journal, 2012 - Wiley Online Library
Olefin metathesis has revolutionized the way chemists design and synthesize molecules,
mostly due to the development of well‐defined ruthenium catalysts with high oxygen …

Chelating alkylidene ligands as pacifiers for ruthenium catalysed olefin metathesis

Y Vidavsky, A Anaby, NG Lemcoff - Dalton Transactions, 2012 - pubs.rsc.org
Olefin metathesis catalysed by ruthenium has emerged at the frontier of modern synthetic
chemistry. The desire to enhance catalyst stability, gain control over the catalytic process …

Photoactivation of ruthenium olefin metathesis initiators

A Ben-Asuly, A Aharoni, CE Diesendruck… - …, 2009 - ACS Publications
UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a
cis-dichloro− trans-dichloro photoisomerization. The enhanced activity of the trans isomer …

Latent and delayed action polymerization systems

S Naumann, MR Buchmeiser - Macromolecular rapid …, 2014 - Wiley Online Library
Various approaches to latent polymerization processes are described. In order to highlight
recent advances in this field, the discussion is subdivided into chapters dedicated to diverse …

Studies on Electronic Effects in O‐, N‐and S‐Chelated Ruthenium Olefin‐Metathesis Catalysts

E Tzur, A Szadkowska, A Ben‐Asuly… - … A European Journal, 2010 - Wiley Online Library
A short overview on the structural design of the Hoveyda–Grubbs‐type ruthenium initiators
chelated through oxygen, nitrogen or sulfur atoms is presented. Our aim was to compare …