Reactions of hydrosilanes with transition metal complexes and characterization of the products
JY Corey - Chemical Reviews, 2011 - ACS Publications
Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …
Recent Advances in Nonclassical Interligand Si... H Interactions
GI Nikonov - Advances in Organometallic Chemistry, 2005 - books.google.com
The discovery by Kubas et al. 1 of the coordination of an intact dihydrogen molecule to
transition metals to form a dihydrogen s-complex 1 was one of the most exciting and …
transition metals to form a dihydrogen s-complex 1 was one of the most exciting and …
Si–H bond activation at {(NHC) 2 Ni 0} leading to hydrido silyl and bis (silyl) complexes: a versatile tool for catalytic Si–H/D exchange, acceptorless dehydrogenative …
D Schmidt, T Zell, T Schaub, U Radius - Dalton Transactions, 2014 - pubs.rsc.org
The unique reactivity of the nickel (0) complex [Ni2 (iPr2Im) 4 (COD)](1)(iPr2Im= 1, 3-di-
isopropyl-imidazolin-2-ylidene) towards hydrosilanes in stoichiometric and catalytic …
isopropyl-imidazolin-2-ylidene) towards hydrosilanes in stoichiometric and catalytic …
Bis(o-phosphinophenyl)silane as a Scaffold for Dynamic Behavior of H−Si and C−Si Bonds with Palladium(0)
J Takaya, N Iwasawa - Organometallics, 2009 - ACS Publications
Synthesis and structural analysis of an unprecedented η2-Si− H complex of mononuclear Pd
(0) was achieved utilizing bis (o-phosphinophenyl) silane as a PSiP pincer-type scaffold for …
(0) was achieved utilizing bis (o-phosphinophenyl) silane as a PSiP pincer-type scaffold for …
Reaction of bis (o-phosphinophenyl) silane with M (PPh 3) 4 (M= Ni, Pd, Pt): synthesis and structural analysis of η 2-(Si–H) metal (0) and pentacoordinate silyl metal (ii …
J Takaya, N Iwasawa - Dalton Transactions, 2011 - pubs.rsc.org
Reactions of bis (o-(diphenylphosphino) phenyl) methylsilane with M (PPh3) 4 (M= Ni, Pd,
Pt) were investigated. When M= Ni or Pd, synthesis and isolation of η2-(Si-H) complexes of …
Pt) were investigated. When M= Ni or Pd, synthesis and isolation of η2-(Si-H) complexes of …
Synthesis and structure of formally hexavalent palladium complexes
W Chen, S Shimada, M Tanaka - Science, 2002 - science.org
Formally hexavalent palladium complexes have been isolated and structurally characterized
for the first time. Thermal condensation reaction of three molecules of 1, 2-C6H4 (SiH2) …
for the first time. Thermal condensation reaction of three molecules of 1, 2-C6H4 (SiH2) …
Structural similarities in dinuclear, tetranuclear, and pentanuclear nickel silyl and silylene complexes obtained via Si–H and Si–C activation
R Beck, SA Johnson - Organometallics, 2012 - ACS Publications
The reactions of (i Pr3P) 2Ni0 precursors with Ph2SiHCl, Ph2SiH2, PhSiH3, and Ph3SiH
provide mononuclear, dinuclear, tetranuclear, and pentanuclear complexes with silyl and …
provide mononuclear, dinuclear, tetranuclear, and pentanuclear complexes with silyl and …
Ruthenium Complexes Containing Two Ru−(η2-Si−H) Bonds: Synthesis, Spectroscopic Properties, Structural Data, Theoretical Calculations, and Reactivity Studies
F Delpech, S Sabo-Etienne, JC Daran… - Journal of the …, 1999 - ACS Publications
The bis (dihydrogen) complex RuH2 (H2) 2 (PCy3) 2 (1) reacts with the disilanes (R2SiH)
2X to produce the dihydride complexes [RuH2 {(η2-HSiR2) 2X}(PCy3) 2](with R= Me and X …
2X to produce the dihydride complexes [RuH2 {(η2-HSiR2) 2X}(PCy3) 2](with R= Me and X …
Multinuclear Pd and Pt complexes with bridging Si-and Ge-ligands. Stable and flexible coordination bonds and structures and reactions of the molecules
Late transition metal complexes with metal-silicon or metal-germanium σsingle bondbond
show the chemical properties that could not be found for the complexes with metal-carbon …
show the chemical properties that could not be found for the complexes with metal-carbon …
Group 10 transition-metal complexes with metal–silicon bonds derived from 1, 2-disilylbenzenes and bis (2-silylphenyl) silane
S Shimada, M Tanaka - Coordination chemistry reviews, 2006 - Elsevier
This article provides an account of the group 10 transition-metal complexes with metal–
silicon bonds formed by the reaction of hydrosilanes with group 10 transition-metal …
silicon bonds formed by the reaction of hydrosilanes with group 10 transition-metal …