Strategies for corrole functionalization
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …
core, as well as the peripheral positions of the macrocycle. Experimental details for the …
Electrochemistry of corroles in nonaqueous media
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …
1980 until the present. The outline of the review is grouped according to the periodic table …
Ligand noninnocence in coinage metal corroles: a silver knife‐edge
A silver β‐octabromo‐meso‐triarylcorrole has been found to exhibit a strongly saddled
geometry, providing the first instance of a strongly saddled corrole complex involving a metal …
geometry, providing the first instance of a strongly saddled corrole complex involving a metal …
Symmetrically Functionalized Copper and Silver Corrole‐Bis‐Tetracyanobutadiene Push‐Pull Conjugates: Efficient Population of Triplet States via Charge Transfer
Copper and silver tritolylcorroles (TTC) are symmetrically functionalized to carry two
tetracyanobutadiene (TCBD) entities via [2+ 2] cycloaddition‐retroeletrocyclization reaction …
tetracyanobutadiene (TCBD) entities via [2+ 2] cycloaddition‐retroeletrocyclization reaction …
Magnetic Circular Dichroism of Porphyrinoid Silver Complexes: Evidence of the Electronic Structure Inversion upon Protonation of the N-Confused Core
DE Nevonen, JC Wagner, C Brückner… - The Journal of …, 2023 - ACS Publications
We report a systematic investigation of a series of Ag (II) and Ag (III) complexes of porphyrins
and their analogues using UV–vis magnetic circular dichroism (MCD) spectroscopies and …
and their analogues using UV–vis magnetic circular dichroism (MCD) spectroscopies and …
Metal complexes of singly, doubly and triply linked porphyrins and corroles: An insight into the physicochemical properties
Metal complexes of multi‐porphyrins and multi‐corroles are unique systems that display a
host of extremely interesting properties. Availability of free meso and β positions allow …
host of extremely interesting properties. Availability of free meso and β positions allow …
Experimental and Theoretical Investigations of the Existence of CuII, CuIII, and CuIV in Copper Corrolato Complexes
W Sinha, MG Sommer, N Deibel, F Ehret… - Angewandte Chemie …, 2015 - Wiley Online Library
The most common oxidation states of copper in stable complexes are+ I and+ II. CuIII
complexes are often considered as intermediates in biological and homogeneous catalysis …
complexes are often considered as intermediates in biological and homogeneous catalysis …
Asymmetric zinc porphyrin-sensitized nanosized TiO 2 for efficient visible-light-driven CO 2 photoreduction to CO/CH 4
Asymmetric zinc porphyrin (ZnPy) was synthesized and used to sensitize nanosized TiO2.
The visible-light-driven activity of CO2 photoreduction to generate CO/CH4 in the gas phase …
The visible-light-driven activity of CO2 photoreduction to generate CO/CH4 in the gas phase …
Synthesis, characterization, and reactivities of high valent metal–corrole (M= Cr, Mn, and Fe) complexes
For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …
relatively lower. However, biological systems in various enzymatic reactions rely extensively …
Photocatalytic C–H thiocyanation of corroles: development of near-infrared (NIR)-emissive dyes
A new method of activating corrole macrocycles via an in situ generated SCN radical has
been developed at very mild conditions at room temperature. This photoredox reaction …
been developed at very mild conditions at room temperature. This photoredox reaction …