The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

Alcohols and carboxylic acids are among the most commercially abundant, synthetically
versatile, and operationally convenient functional groups in organic chemistry. Under visible …

Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …

The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

A dual photochemical/nickel-mediated decarboxylative strategy for the assembly of C (sp3)–
C (sp2) linkages is disclosed. Under light irradiation at 390 nm, commercially available and …

Ni/photoredox catalysis has emerged as a powerful platform for C (sp2)–C (sp3) bond
formation. While many of these methods typically employ aryl bromides as the C (sp2) …