The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Since their development in the 1970s, cross-coupling reactions catalyzed by transition
metals have become one of the most important tools for constructing both carbon− carbon …

Alcohols and their derivatives are ubiquitous and versatile motifs in organic synthesis.
Deoxygenative transformations of these compounds are often challenging due to the …

Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …

Das Gebiet der übergangsmetallkatalysierten direkten Arylierung unter C‐H‐Bindungsbruch
hat in den letzten Jahren eine rasante Entwicklung erfahren, was dazu führte, dass sich …

Enol and phenol functionalities are very common in organic molecules. Utilization of these
materials is very appealing in organic synthesis because they are important alternatives to …

A catalytic method to prepare highly substituted 1, 3-dienes from two different alkenes is
described using a directed, palladium (II)-mediated C (alkenyl)–H activation strategy. The …

Herein, we report a regioselective alkenyl electrophile synthesis from unactivated olefins
that is based on a direct and regioselective C− H thianthrenation reaction. The selectivity is …

The aryl‐to‐vinyl nickel 1, 4‐migration (1, 4‐Ni migration) reaction has been reported for the
first time. The generated alkenyl Ni species undergo a reductive coupling reaction with …