The field of carbon dioxide reduction by homogeneous early transition complexes (groups 3–
7) is reviewed. Many reactions with CO 2 have been studied with late transition metal …

There is tremendously increasing interest in the reductive conversion of CO2 into liquid fuel
and value-added oxygenated multi-carbons (C2+) to solve the environmental and energy …

We resolve the long-standing controversy about the first step of the CO2 electroreduction to
fuels in aqueous electrolytes by providing direct spectroscopic evidence that the first …

Contemporary studies emphasize that superoxide radical (O 2∙-) exhibits the potential to
degrade organic contaminants, but practical application of this radical in engineered waters …

Abstract 2, 2′: 6′, 2′′‐Terpyridine (tpy) and its derivatives represent highly versatile
ligands for the complexation of transition metal ions. Today, such complexes are employed …

Regulation of the radical pair spin states allows effective optimization of the electrocatalytic
CO2 reduction reaction. This study for the first time reports an experimental observation of …

CO2 electroreduction is among the most promising approaches used to transform this green-
house gas into useful fuels and chemicals. Ionic liquids (ILs) have already proved to be the …

Three crystalline heterometallic molybdenum (V) phosphates have been synthesized under
hydrothermal conditions. They all contain {M [P4Mo6O28 (OH) 3] 2} 16–[M= Mn (II) or Co (II)] …

Redox chemistry during the activation of carbon dioxide involves changing the charge state
in a CO2 molecular unit. However, such changes are usually not well described by integer …

The photochemistry of SO2 at the air–water interface of water droplets leads to the formation
of HOSO radicals. Using first-principles simulations, we show that HOSO displays an …