Although organotransition metal chemistry has long been dominated by compounds
containing closed-shell electron configurations and obeying the 18-electron rule, 1 there has …

The study of mixed-valence compounds has a long and intriguing history [1, 2]. For more
than 'two centuries after the discovery of the first mixed-valence compound, Prussian blue [3 …

Transition-metal organometallic chemistry has been so far dominated by the16e/18e rule. 1,
2 Indeed, in most isolable complexes, the transition metal bears such numbers of electrons …

The oxidation chemistry of the organometallic hydride complexes (rj5-C5H5) M (CO) 3H (M=
Cr, 1; Mo, 2; W, 3),(t) 5-C5Me5) Mo (CO) 3H (4), and (7i5-C5H5) W (CO) 2 (PMe3) H (5) has …

A new family of molecule-based magnets of general formula V [TCNQR2] 2⊙ z CH2Cl2 has
been synthesized and characterized (TCNQ= 7, 7, 8, 8-tetracyano-p-quinodimethane; R= H …

Organometallic chemistry has traditionally been the domain of diamagnetic complexes and
the powerful 16-and 18-electron rule. 1 This rule, as set forth by Tolman, 1 (a) states that “ …

This series, Mechanisms of Inorganic and Organometallic Reactions, provides an ongoing
critical review of the published literature concerned with the mechanisms of reactions of …

VII [TCNE]-z [TCNE] 2-1-z/2 (1< z< 2) is the simplest formulation for the inhomogeneous and
nonstoichiometric V [TCNE] x (x= 1+ z/2) room temperature magnet. This is based upon …

5327 Angew. Chem. Int. Ed. 2006, 45, 5326–5331 2006 Wiley-VCH Verlag GmbH & Co.
KGaA, Weinheim www. angewandte. org bases.[23] Nonetheless, absorptions in these …

The emphasis on climate change requires processes to be more efficient to minimize CO2
emissions, and nanostructured materials as catalysts could play a crucial role due to their …