Atomic-scale observations of catalyst structures under reaction conditions and during catalysis

F Tao, PA Crozier - Chemical reviews, 2016 - ACS Publications
Heterogeneous catalysis is a chemical process performed at a solid–gas or solid–liquid
interface. Direct participation of catalyst atoms in this chemical process determines the …

Methane decomposition to COx-free hydrogen and nano-carbon material on group 8–10 base metal catalysts: a review

Y Li, D Li, G Wang - Catalysis today, 2011 - Elsevier
Methane catalytic decomposition is a promising process that simultaneously produces COx-
free hydrogen and carbon nanomaterial. The hydrogen produced can be consumed directly …

Atomic-scale in-situ observation of carbon nanotube growth from solid state iron carbide nanoparticles

H Yoshida, S Takeda, T Uchiyama, H Kohno… - Nano …, 2008 - ACS Publications
We have first observed the nucleation and growth process of carbon nanotubes (CNTs) from
iron carbide (Fe3C) nanoparticles in chemical vapor deposition with C2H2 by in situ …

[HTML][HTML] Carbon nanotubes–becoming clean

N Grobert - Materials today, 2007 - Elsevier
Carbon nanotubes (CNTs) are now well into their teenage years. Early on, theoretical
predictions and experimental data showed that CNTs possess chemical and mechanical …

The importance of strong carbon− metal adhesion for catalytic nucleation of single-walled carbon nanotubes

F Ding, P Larsson, JA Larsson, R Ahuja, H Duan… - Nano …, 2008 - ACS Publications
Density functional theory is used to show that the adhesion between single-walled carbon
nanotubes (SWNTs) and the catalyst particles from which they grow needs to be strong to …

Imaging of transient structures using nanosecond in situ TEM

JS Kim, T LaGrange, BW Reed, ML Taheri… - Science, 2008 - science.org
The microstructure and properties of a material depend on dynamic processes such as
defect motion, nucleation and growth, and phase transitions. Transmission electron …

Evolution of Glassy Carbon Microstructure: In Situ Transmission Electron Microscopy of the Pyrolysis Process

S Sharma, CN Shyam Kumar, JG Korvink, C Kübel - Scientific reports, 2018 - nature.com
Glassy carbon is a graphene-rich form of elemental carbon obtained from pyrolysis of
polymers, which is composed of three-dimensionally arranged, curved graphene fragments …

Mechanisms for catalytic carbon nanofiber growth studied by ab initio density functional theory calculations

F Abild-Pedersen, JK Nørskov, JR Rostrup-Nielsen… - Physical Review B …, 2006 - APS
Mechanisms and energetics of graphene growth catalyzed by nickel nanoclusters were
studied using ab initio density functional theory calculations. It is demonstrated that nickel …

Interactions between metals and carbon nanotubes: at the interface between old and new materials

F Banhart - Nanoscale, 2009 - pubs.rsc.org
The article reviews the interaction between crystalline metals and carbon nanotubes in
nanocomposite systems. Starting with an introduction to the chemical interaction between …

Imaging catalysts at work: a hierarchical approach from the macro‐to the meso‐and nano‐scale

JD Grunwaldt, JB Wagner… - ChemCatChem, 2013 - Wiley Online Library
This review highlights the importance of developing multi‐scale characterisation techniques
for analysing operating catalysts in their working environment. We emphasise that a …