Biomass fractionation and lignin fractionation towards lignin valorization

J Xu, C Li, L Dai, C Xu, Y Zhong, F Yu, C Si - ChemSusChem, 2020 - Wiley Online Library
Lignin, as the most abundant aromatic biopolymer in nature, has attracted great attention
due to the complexity and richness of its functional groups for value‐added applications. The …

Stabilization strategies in biomass depolymerization using chemical functionalization

YM Questell-Santiago, MV Galkin, K Barta… - Nature Reviews …, 2020 - nature.com
A central feature of most lignocellulosic-biomass-valorization strategies is the
depolymerization of all its three major constituents: cellulose and hemicellulose to simple …

[HTML][HTML] The isolation of lignin with native-like structure

Z Wang, PJ Deuss - Biotechnology Advances, 2023 - Elsevier
Searching for renewable alternatives for fossil carbon resources to produce chemicals, fuels
and materials is essential for the development of a sustainable society. Lignin, a major …

Sustainable preparation of cellulose nanocrystals: state of the art and perspectives

M Gao, Y Shang, B Li, H Du - Green Chemistry, 2022 - pubs.rsc.org
As sustainable and advanced nanomaterials, cellulose nanocrystals (CNCs) attract
extensive attention from both academia and industry due to their superior physical and …

One-pot protolignin extraction by targeted unlocking lignin–carbohydrate esters via nucleophilic addition–elimination strategy

Y Lou, X Sun, Y Yu, S Zeng, Y Li, Y Liu, H Yu - Research, 2023 - spj.science.org
Protolignin extraction can facilitate structure elucidation and valorization of lignin in
biorefinery, but is rather challenging due to the complex chemical bonds present. Here, we …

A biomass pretreatment using cellulose-derived solvent Cyrene

X Meng, Y Pu, M Li, AJ Ragauskas - Green Chemistry, 2020 - pubs.rsc.org
Despite only recently becoming available in the quantities required for solvent usage, the
cellulose-derived solvent, named Cyrene, has gained significant attention in green …

Acid hydrotropic fractionation of lignocelluloses for sustainable biorefinery: advantages, opportunities, and research needs

J Zhu, L Chen, C Cai - ChemSusChem, 2021 - Wiley Online Library
This Minireview provides a comprehensive discussion on the potential of using acid
hydrotropes for sustainably fractionating lignocelluloses for biorefinery applications. Acid …

Maleic acid as a dicarboxylic acid hydrotrope for sustainable fractionation of wood at atmospheric pressure and≤ 100 C: mode and utility of lignin esterification

C Cai, K Hirth, R Gleisner, H Lou, X Qiu, JY Zhu - Green Chemistry, 2020 - pubs.rsc.org
This study evaluated maleic acid (MA) as a green hydrotrope for efficient wood fractionation
at atmospheric pressure and≤ 100° C. MA hydrotropic fractionation (MAHF) resulted in …

Lignin deoxygenation for the production of sustainable aviation fuel blendstocks

MS Webber, J Watson, J Zhu, JH Jang, M Çağlayan… - Nature Materials, 2024 - nature.com
Lignin is an abundant source of renewable aromatics that has long been targeted for
valorization. Traditionally, the inherent heterogeneity and reactivity of lignin has relegated it …

Flow-through solvolysis enables production of native-like lignin from biomass

DG Brandner, JS Kruger, NE Thornburg, GG Facas… - Green …, 2021 - pubs.rsc.org
The inherent reactivity of lignin in conventional biomass processing commonly prevents
isolation of native lignin and limits monomer yields from catalytic depolymerization strategies …